Hitachi CHROMASTER 5160, Instruction Manual

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Table 3-2 Characteristics of Organic Solvents
Ignition Point
Polarity
E
2
(Al
2
O
3
)
Viscosity
(cP20
°
C)
Refractive
Index UV Cut
off (nm) Flash
Point (
°
C)
°
C
Lower
Limit Upper
Limit
Vapor
Density
(Air: 1)
Boiling
Point (
°
C)
Specific
Gravity
(Water: 1)
Fluoroalkanes -0.25 1.25
n-Pentane 0.00 0.23 1.358 210 < -40 308.9 1.5 7.8 2.5 36.1 0.6
Hexane 0.00 1.375 210 -21.7 233.9 1.2 7.5 3.0 68.9 0.7
Isooctane 0.01 1.404 210
Petroleum ether 0.01 0.3 210
n-Decane 0.04 0.92 1.412 46.1 207.8 0.8 5.4 4.9 173.9 0.7
Cyclohexane 0.04 1.00 1.427 210 -20 260 1.3 8 2.9 81.7 0.8
Cyclopentane 0.05 0.47 1.406 210
Diisobutylene 0.06 1.411 210
i-Pentene 0.08 1.371 -17.8 272.8 1.5 8.7 2.4 30 0.7
Carbon disulfide 0.15 0.37 1.626 380 -30 100 1.3 44 2.6 46.1 1.3
Carbon tetrachloride 0.18 0.97 1.466 265
Amyl chloride 0.26 0.43 1.413 225 12.8 343.3 1.6 8.6 3.7 106.1 0.9
Butyl chloride 0.26 1.436 220 -9.4 460 1.8 10.1 3.2 0.9
0.81 † o-17.2 463.9 1.0 6.0 144.4
Xylene 0.26 0.61 † ~ 1.50 290 m-25 527.8 1.1 7.0 3.7 138.9 0.9
0.64
†
p-25 528.9 1.1 7.0 138.3
i-Propyl ether 0.28 1.368 220 -27.8 443.3 1.4 21 3.5 68.9 0.7
i-Propyl chloride 0.29 0.37 1.378 225 -32.2 593.3 2.8 10.7 2.7 35 0.9
Toluene 0.29 0.33 1.496 285 4.4 536.1 1.4 6.7 3.1 110.6 0.9
n-Propyl chloride 0.30 0.59 1.389 225 < -17.8 2.6 11.1 2.7 46.1 0.9
Chlorobenzene 0.30 0.35 1.525 32.2 637.8 1.3 7.1 3.9 132.2 1.1
Benzene 0.32 0.80 1.501 280 -11.1 562.2 1.4 7.1 2.8 80 0.9
Ethyl bromide 0.37 0.65 1.424 511.1 6.7 11.3 3.8 37.8 1.4
Ethyl ether 0.38 1.353 220 -45 180 1.9 48 2.6 35 0.7
Ethyl sulfide 0.38 0.23 1.442 290
Chloroform 0.40 0.45 1.443 245
Methylene chloride 0.42 0.57 1.424 245 -50 518.9 3.8 15.4 2.2 38.5 0.9
Methyl i-butyl ketone 0.43 0.44 1.394 330
Tetrahydrofurane 0.45 1.408 220 -14.4 321.1 2 11.8 2.5 66.1 0.9
Ethylene dichloride 0.49 1.445 230 13.3 412.3 6.2 16 3.4 83.9 1.3
Methyl ethyl ketone 0.51 0.79 1.381 330 -6.1 515.6 1.8 10 2.5 80 0.8
i-Nitropropane 0.53 1.400 380 48.9 420.6 2.6 3.1 131.1 1.0
Acetone 0.56 1.359 220 -17.8 537.8 2.6 12.8 2.0 56.7 0.8
Dioxane 0.56 0.32 1.422 260 12.2 180 2.0 22 3.0 101.1 1.0
Ethyl acetate 0.58 1.54 1.370 260 4.4 460 1.8 8 3.5 90 0.9
Methyl acetate 0.60 0.45 1.362 210 -10 501.7 3.1 16 2.6 60 0.9
Amyl alcohol 0.61 0.37 1.410 32.8 300 1.2 10.0 3.0 137.8 0.8
Dimethyl sulfoxide 0.62 4.1
Aniline 0.62 2.24 1.586 70 617.2 1.3 3.2 184.4 1.0
Dimethyl amine 0.63 4.4 1.387 275 < -17.8 312.2 1.8 10.1 2.5 56.7 0.7
Nitromethane 0.64 0.38 1.394 380 35 418.3 7.3 2.1 101.1 1.1
Acetonitrile 0.65 0.67 1.344 210 5.6 1.4 81.7 0.8
Pyridine 0.71 0.37 1.510 305 20 1.8 12.4 2.7 115 1.0
Butyl cellosolve 0.74 0.94 220
i-Propanol n-Propanol 0.82 1.38 210 11.7 398.9 2.0 12 2.1 82.8 0.8
Ethanol 0.88 2.3 1.361 210 12.8 422.8 4.3 19 1.6 78.3 0.8
Methanol 0.95 1.20 1.329 210 11.1 463.9 7.3 36 1.1 63.9 0.8
Ethylene glycol 1.11 0.60 1.427 210 111.1 412.8 3.2 197.2 1.1
Acetic acid Large 19.9 1.372
Water Large 1.26 1.333
Salts & buffer Larger
* L.R.Snydar, Dekker. “Principles of Adsorption Chromatography”
† The Handbook of Chemistry, 2nd ed., The Chemical Society of Japan
Solvent with low boiling point as shown in cannot be used.
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