SCIEX TripleTOF 5600, Руководство пользователя системы

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Table B-1 PPG Exact Masses (continued)
(M + COOH)
–
(M + NH
4
)
2+
MSMS
Fragments
(M + NH
4
)
+
Exact Mass (M) n
991.67851 491.37398 929.67704 964.71414 946.68032 16
1049.72037 520.39491 987.71890 1022.75600 1004.72218 17
1107.76223 549.41584 1045.76076 1080.79786 1062.76404 18
1165.80409 578.43677 1103.80262 1138.83972 1120.80590 19
1223.84595 607.45770 1161.84448 1196.88158 1178.84776 20
1281.88781 636.47863 1219.88634 1254.92344 1236.88962 21
1339.92967 665.49956 1277.92820 1312.96530 1294.93148 22
Reserpine
Table B-2 Reserpine Exact Masses
Reserpine (C
33
H
40
N
2
O
9
)
Mass Description
609.28066 Molecular Ion C
33
H
41
N
2
O
9
448.19659 Fragment C
23
H
30
NO
8
397.21218 Fragment C
23
H
29
N
2
O
4
365.18597 Fragment C
22
H
25
N
2
O
3
236.12812 Fragment C
13
H
18
NO
3
195.06519 Fragment C
10
H
11
O
4
174.09134 Fragment C
11
H
12
NO
Taurocholic Acid
Table B-3 Taurocholic Acid Exact Masses
Taurocholic Acid (C
26
H
45
NO
7
S)
Mass Description
514.28440 Molecular Ion C
26
H
44
NO
7
S
106.98084 Fragment C
2
H
3
O
3
S
System User Guide TripleTOF
®
5600/5600+ System
RUO-IDV-05-7040-B 114 / 131
Exact Masses and Chemical Formulas