
28
TITRATION THEORY
6
GLOSSARY
Acid
A chemical species that can donate one or more protons (hydrogen ions).
Acid-Base Titration
Stoichiometric neutralization titrations, based upon the reaction that occurs between
an acid and base.
Activity
A physical property corresponding to the concentration of all ions in a solution.
Electrodes respond to activity.
Amperometric Titration
Titrations where the current flow between two electrodes (often a metal electrode and
a reference electrode) are used to monitor the titration progress.
Analyte
The chemical species being measured in a titration.
Argentometric Titration
Titrations that use silver (nitrate) as the titrant. These titrations are typically precipitation
titrations.
Automatic Titrator
An instrument designed to automatically carry out a titration. It will add the appropriate
amount of titrant, determine the end-point and calculate the results.
Back Titration
A type of titration where an excess amount of titrant is added to a sample forcing a
sluggish reaction to go to completion. The excess reagent is then “back” titrated with
a second titrant.
Base
A chemical species that can accept one or more protons (hydrogen ions).
Biamperometric Indication
Uses a double platinum pin electrode to measure the current flow through a titration
solution.
Bivoltametric Indication
Uses a double platinum pin electrode to measure the voltage required to maintain a
constant current flow through a titration solution while constant voltage is applied
across the platinum elements of the electrode.
Burette
A graduated cylindrical piece of laboratory glassware that is used to dispense precise
amounts of solution.
Complex Ion
A species where a central metal ion is covalently bonded to one or more electron
donating groups called ligands.
Complexometric Titrations
Metal ions are titrated using a titrant that binds strongly to it. The titrants often
contain Ethylenediaminetetraacetic Acid (EDTA) or Cyclohexylenedinitrilotetraacetic
Acid (CDTA).
Summary of Contents for HI 904
Page 1: ...1 QUICK START GUIDE HI 904 KARL FISCHER COULOMETRIC TITRATOR Revision 1 0 www hannainst com...
Page 4: ...4 QUICK START GUIDE...
Page 7: ...7 QUICK START GUIDE TITRATOR CONNECTIONS Front View Rear View...
Page 17: ...1 INSTRUCTION MANUAL HI 904 KARL FISCHER COULOMETRIC TITRATOR Revision 1 00 www hannainst com...
Page 20: ...4...
Page 22: ...1 2 INTRODUCTION...
Page 24: ...2 2 SETUP...
Page 27: ...2 5 SETUP 2 3 Installation 2 3 1 Titrator Top View...
Page 28: ...2 6 SETUP 2 3 2 Titrator Rear View 2 3 3 Titrator Left side View...
Page 38: ...3 2 USER INTERFACE...
Page 46: ...3 10 USER INTERFACE...
Page 48: ...4 2 GENERAL OPTIONS...
Page 82: ...5 24 METHODS...
Page 84: ...6 2 TITRATION...
Page 94: ...6 12 TITRATION...
Page 96: ...7 2 AUXILIARY FUNCTIONS...
Page 104: ...8 2 MAINTENANCE PERIPHERALS...
Page 112: ...8 10 MAINTENANCE PERIPHERALS...
Page 124: ...9 12 METHODS OPTIMIZATION...
Page 125: ...A3 2 APPENDIX 3...
Page 126: ...A3 6 APPENDIX 3 MAN HI904 09 13...
Page 127: ...A1 1 APPENDIX 1 Appendix 1 Contents A1 TECHNICAL SPECIFICATIONS A1 3...
Page 128: ...A1 2 APPENDIX 1...
Page 132: ...A2 2 APPENDIX 2...
Page 134: ...A2 4 APPENDIX 2...
Page 135: ...A3 1 APPENDIX 3 Appendix 3 Accessories A3 TITRATOR COMPONENTS A3 3...
Page 136: ...A3 2 APPENDIX 3...
Page 140: ...A3 6 APPENDIX 3 MAN HI904 09 13...
Page 141: ...1 GENERAL APPLICATIONS BROCHURE HI 904 KARL FISCHER COULOMETRIC TITRATOR www hannainst com...
Page 142: ......
Page 144: ......
Page 146: ......
Page 150: ...2 TITRATION THEORY...
Page 166: ...18 TITRATION THEORY A B Figure 8 Potential glass electrode mV C...