Electrochemical corrosion
60
Metals susceptible to corrosion
All metals can be physically listed in a galvanic po-
tential series. This indicates the metal’s normal po-
tential (voltage) in relation to a reference electrode
when each material is immersed in a particular elec-
trolyte.
The following is a voltage series for metals. The elec-
trolyte is seawater at a temperature range of +0°C
to +26.7°C (50°F – 80°F). The water flow rate is 2.4
– 4.0 m/s (7.8-3. ft/s).
The reference electrode is silver-silver chloride
(Ag-AgCl).
Graphite
+0.9 to +0.25 V
Stainless steel 8-8, Mo,
in a passive state *
±0.00 to -0.0 V
Stainless steel 8-8
in a passive state *
-0.05 to -0.0 V
Nickel
-0.0 to -0.20 V
Nickel aluminum bronze
-0.3 to -0.22 V
Lead
-0.9 to -0.25 V
Silicon bronze (Cu, Zn, Si, Mn, Sn)
-0.26 to
-0.29 V
Manganese bronze (Cu, Zn, Sn, Fe, Mn)
-0.27 to -0.34 V
Aluminum brass (Cu, Zn, Al)
-0.28 to -0.36 V
Soft solder (Pb, Sn)
-0.28 to -0.37 V
Copper
-0.30 to -0.57 V
Tin
-0.3 to -0.33 V
Red brass (Cu, Zn)
-0.30 to -0.40 V
Yellow brass (Cu, Zn)
-0.30 to -0.40 V
Aluminum bronze
-0.3 to -0.42 V
Stainless steel 8-8, Mo,
in an active state **
-0.43 to -0.54 V
Stainless steel 8-8 in an active state **
-0.46 to -0.58 V
Cast iron
-0.60 to -0.7 V
Steel
-0.60 to -0.7 V
Aluminum alloys
-0.76 to -.00 V
Galvanized iron and steel
-0.98 to -.03 V
Zinc
-0.98 to -.03 V
Magnesium and magnesium alloys
consumed
-.60 to -.63V
* Metals are in a passive state when the metal has a thin, reac-
tion-inhibiting coating. This coating is not present in an active state.
** Still water.
From the table, we can see that steel has about -0.65
V and aluminum around -0.85 V in the voltage se-
ries. The higher up in the voltage series (the greater
potential), the more noble the metal. If these metals
are connected together in a galvanic element, the
less noble metal will be consumed by the more noble
metal-galvanic corrosion arises.
In our case, the aluminum will corrode.
The further the metals are apart in the galvanic volt-
age series, the greater the (corrosive) effect will be
on the less noble metal if they are connected togeth-
er in a galvanic element.
Definitions
One-pole system
In a -pole system the engine block itself is used as
a negative return for all electrical components on the
engine block.
Two-pole system
All engines covered in this manual have a two-pole
electrical system. This means that each electrical
component on the engine has an insulated DC nega-
tive return. The alternator, starter motor and all sen-
sors are electrically isolated from the engine block
and the positive and negative poles of the batteries
must be connected to the starter motor terminal.
Isolation Transformer
A transformer with galvanically separated input and
output windings.
Galvanic isolator
A device installed in series with the AC grounding
conductor of the shore power cable to prevent low
voltage DC galvanic current flow, but permit the pas-
sage of alternating current normally associated with
the AC grounding conductor.
Ground fault circuit interrupter (GFCI)
A device for the protection of personnel. The GFCI
de-energize a circuit, when a current to ground ex-
ceeds a predetermined value.
Содержание D11 series
Страница 1: ...Marine Propulsion Diesel Engines Installation 1 1 D E D5 D16 series ...
Страница 2: ......
Страница 208: ...206 References to Service Bulletins Group No Date Concerns ...
Страница 209: ...207 Notes ...
Страница 210: ...208 Notes ...
Страница 212: ...7748655 English 11 2007 ...