ASAP 2460 Operator’s Manual
Appendix F
246-42800-01 - Aug 2013
F-5
Figure
D
-2. Model Isotherm for Argon at 87.3 K in a 40 Å Slit in a Carbon Substrate
The profiles show the density distribution from one wall to the center of the slit; the other half of the
distribution is a mirror image of the profile shown.
As the pressure is first increased from zero, almost all the adsorbed atoms occupy a position close to
the surface.
• Inset
a
shows the profile corresponding to point a on the isotherm where the surface is about half
covered.
• At point
b
, the first layer is so full that it is more favorable for atoms to start a new layer.
• At point
c
, a third layer is forming. Point c, for this size slit, is the critical pore-filling pressure. In
inset c, the profile shows the density decreasing to near zero (actually the bulk gas density) at 4 or 5
molecular diameters from the surface.
• Inset
d
shows the profile converging on a density similar to that of bulk liquid argon in the center of
the pore, indicating a phase transition.
Note that the adsorption isotherms for pores larger than the one shown in
Figure D-2
is identical up to
point
c
. The lower branch of the isotherm simply continues to a higher pressure for larger pores. This
trend is illustrated in
Figure D-3
, where isotherms for some larger size pores are shown. It is clear that
pore size is uniquely characterized by a corresponding critical pore-filling pressure. At large pore
sizes, density functional theory produces results for the critical filling pressures that are in good agree-
ment with those produced by the Kelvin equation.
Summary of Contents for ASAP 2460
Page 4: ......
Page 12: ...Table of Contents ASAP 2460 Operator s Manual viii 246 42800 01 Nov 2013...
Page 30: ...Using the Software ASAP 2460 Operator s Manual 1 18 246 42800 01 Aug 2013...
Page 93: ...ASAP 2460 Operator s Manual Generating Graph Overlays 246 42800 01 Aug 2013 2 63...
Page 94: ...Generating Graph Overlays ASAP 2460 Operator s Manual 2 64 246 42800 01 Aug 2013...
Page 202: ...Service Test ASAP 2460 Operator s Manual 4 36 246 42800 01 Aug 2013...
Page 230: ...Report Examples 2460 Operator s Manual 5 28 246 42800 01 Aug 2013 Isotherm Linear Plot...
Page 231: ...2460 Operator s Manual Report Examples 246 42800 01 Aug 2013 5 29 BET Surface Area Report...
Page 232: ...Report Examples 2460 Operator s Manual 5 30 246 42800 01 Aug 2013 BET Surface Area Plot...
Page 233: ...2460 Operator s Manual Report Examples 246 42800 01 Aug 2013 5 31 t Plot Report...
Page 236: ...Report Examples 2460 Operator s Manual 5 34 246 42800 01 Aug 2013...
Page 242: ...Service Test Mode 2460 Operator s Manual 6 6 246 42800 01 Aug 2013...
Page 270: ...Calibrating the System ASAP 2460 Operator s Manual 7 28 246 42800 01 Aug 2013...
Page 276: ...Ordering Information ASAP 2460 Operator s Manual 8 6 246 42800 01 Aug 2013...
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Page 374: ...Appendix C ASAP 2460 Operator s Manual C 50 246 42800 01 Aug 2013...
Page 398: ...Appendix F ASAP 2460 Operator s Manual F 18 246 42800 01 Aug 2013...
Page 412: ...Index ASAP 2460 Operator s Manual Index 8 246 42800 01 Aug 2013...
Page 413: ...ASAP 2460 Operator s Manual Appendix G Aug 2013 SVP 1 SVP Smart VacPrep Operator Manual...
Page 414: ...Appendix G ASAP 2460 Operator s Manual SVP 2 Aug 2013...
Page 422: ...Contact Us vi Smart VacPrep Operator Manual...
Page 432: ...2 About the Software 2 4 Smart VacPrep Operator Manual...
Page 466: ...8 Error Messages 8 4 Smart VacPrep Operator Manual...