CALIDO
Sanitary
water
heat
pump
9
Environmental
precautions:
Volatile
Cleaning
methods:
Volatile
HANDLING
AND
STORAGE
7.1.
Safe
‐
handling
precautions
Safe
use
of
the
product:
The
product
must
be
handled
in
accordance
with
good
industrial
hygiene
and
safety
practices.
Only
experienced
and
properly
instructed
persons
can
manipulate
gases
under
pressure.
Do
not
smoke
while
handling
the
product.
Use
only
specific
equipment
that
are
suitable
for
the
product
and
for
the
operating
pressure
and
temperature.
In
case
of
doubt,
please
contact
the
supplier.
Do
not
breathe
the
gas.
Don’t
release
the
product
in
the
atmosphere.
You
must
ensure
sufficient
air
exchange
and/or
suction.
Do
not
use
direct
flame
or
electric
heating
to
increase
internal
pressure.
Do
not
remove
or
render
illegible
the
affixed
supplier
identification
labels.
Do
not
undergo
any
pressure
test
with
the
air
/HFC
‐
134a
mixtures.
Gas
‐
air
can
form
a
combustible
mixture
at
pressures
higher
than
the
atmospheric
one
when
the
volume
ratio
exceeds
60%.
Storage:
Keep
the
unit
away
from
incompatible
products
such
as:
explosive,
flammable
materials,
Organic
peroxide
EXPOSURE
CONTROL
/
INDIVIDUAL
PROTECTION
8.1.
Control
parameters
DNEL:
Derived
level
without
effect
(workers)
Effects
of
long
‐
term
‐
systemic
effects,
inhalation
14000
mg/m³
PNEC
=
Predicted
No
Effect
Concentration
Water
(soft
water)
0,1
mg/l
Wate
(Sea
water)
0,01
mg/l
Aquatic,
intermittent
releases
1
mg/l
Sediment,
soft
water
0,75
mg/kg
dry
weight
PNEC
for
microorganisms
or
wastewater
treatment
plant
73
mg/l
8.2.
Exposure
controls
Protection
of
eyes:
Total
protective
glasses.
Protective
goggles
should
be
worn
during
the
refilling
operations.
EN
166
‐
Personal
eye
protection
Protection
of
hands:
Protective
gloves
should
be
worn
when
handling
gas
containers.
EN
388
‐
Protective
gloves
against
mechanical
risks.
Generic
protection:
Safety
shoes
should
be
worn
when
handling
containers
EN
ISO
20345
‐
Personal
protective
equipment
‐
Safety
footwear
Respiratory
protection:
Under
‐
oxygenated
environments,
a
breathing
apparatus
or
mask
breathing
air
supply
system
must
be
used.
EN
137
‐
Respiratory
protective
devices
‐
Self
‐
contained
open
‐
circuit
compressed
air
breathing
apparatus
with
full
face
mask.
Hygiene
measures:
Don’t
smoke.
8.2.3.
Environmental
exposure
controls
Refer
to
local
legislation
for
restrictions
to
emissions
in
the
atmosphere.
See
the
section
on
specific
gas
treatment
/
disposal
methods.
PHYSICAL
AND
CHEMICAL
PROPERTIES
9.1.
Basic
information
about
the
Physical
and
Chemical
properties
.
Aspet:
Physical
state
at
20°C
/
101.3kPa:
Colorless
liquefied
gas.
Odor:
Similar
to
ether.
Olfactory
threshold:
The
olfactory
threshold
is
subjective
and
inadequate
to
warn
of
overexposure.
Melting
point
‐
101°C
Boiling
point:
‐
26.5°C
Ignition
point:
Not
flammable
Critical
temperature
[°C]
101°C
Relative
density,
gas
(air
=
1):
3,6
Water
solubility:
1930
mg/l
9.2.
Other
information
Gas/vapor
more
heavier
than
air.
May
accumulate
in
confined
spaces,
particularly
at
or
below
ground
level.
STABILITY
AND
REACTIVITY
Stability:
No
reactivity
if
used
with
the
appropriate
instructions.
Incompatible
materials:
Humidity.
Refer
to
ISO
11114
standard
for
further
information
on
material
compatibility.
Hazardous
decomposition
products:
Halogen
acids,
carbon
dioxide
(CO
2
),
carbon
monoxide,
fluorocarbons,
carbonyl
halides.
Dangerous
reactions:
The
product
is
not
flammable
in
contact
with
air
under
normal
conditions
of
temperature
and
pressure.
Under
pressure
with
air
or
oxygen,
the
mixture
can
become
flammable.
Some
mixtures
of
HCFC
or
HFC
and
chlorine
may
become
flammable
or
reactive
under
certain
conditions.
TOXICOLOGICAL
INFORMATION
Acute
toxicity:
LC50
/
inhalation
/
4
hours
/
on
rat>
567000
ppm
/
4h
EC50
48h
‐
Daphnia
magna>
930
mg/l
LC50
96h
‐
Fish>
450
mg
/
l
No
known
effect
of
this
product.
Local
effects:
Concentrations
substantially
above
the
TLV
(1000
ppm)
value
may
cause
narcotic
effects.
Inhalation
of
decomposition
products
in
high
concentration
may
cause
shortness
of
breath
(lung
oedema)
Long
‐
term
toxicity:
Did
not
show
carcinogenic,
teratogenic
or
mutagenic
effects
on
animal
experiments.
Can
cause
cardiac
arrhythmia.
Limit
threshold
for
cardiac
sensitivity:
312975
mg/m
3
.
Limit
threshold
for
anesthetic
effects:
834600
mg/m
3
Summary of Contents for CALIDO 110
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