
26
Enertech Global
IOM, BS/BT Models
Water Quality
The quality of the water used in geothermal systems is very important. In closed loop systems the dilution
water (water mixed with antifreeze) must be of high quality to ensure adequate corrosion protection. Water
of poor quality contains ions that make the fluid “hard” and corrosive. Calcium and magnesium hardness
ions build up as scale on the walls of the system and reduce heat transfer. These ions may also react
with the corrosion inhibitors in glycol based heat transfer fluids, causing them to precipitate out of solution
and rendering the inhibitors ineffective in protecting against corrosion. In addition, high concentrations
of corrosive ions, such as chloride and sulfate, will eat through any protective layer that the corrosion
inhibitors form on the walls of the system.
Ideally, de-ionized water should be used for dilution with antifreeze solutions since de-ionizing removes
both corrosive and hardness ions. Distilled water and zeolite softened water are also acceptable. Softened
water, although free of hardness ions, may actually have increased concentrations of corrosive ions and,
therefore, its quality must be monitored. It is recommended that dilution water contain less than 100 PPM
calcium carbonate or less than 25 PPM calcium plus magnesium ions; and less than 25 PPM chloride or
sulfate ions.
In an open loop system the water quality is of no less importance. Due to the inherent variation of the
supply water, it should be tested prior to making the decision to use an open loop system. Scaling of the
heat exchanger and corrosion of the internal parts are two of the potential problems. The Department of
Natural Resources or your local municipality can direct you to the proper testing agency. Please see Table
8 for guidelines.
Potential
Problem
Chemical(s) or Condition
Range for Copper
Heat Exchangers
Range for Cupro-Nickel
Heat Exchanger
Range Stainless Steel
Heat Exchanger
Scaling
Calcium & Magnesium
Carbonate
Less than 350 ppm
Less than 350 ppm
Less than 350 ppm
Corrosion
pH Range
7 - 9
5 - 9
7 - 9
Total Dissolved Solids
Less than 1000 ppm
Less than 1500 ppm
Less than 1500 ppm
Ammonia, Ammonium
Hydroxide
Less than 0.5 ppm
Less than 0.5 ppm
Less than 0.5
Ammonium Chloride,
Ammonium Nitrate
Less than 0.5 ppm
Less than 0.5 ppm
Less than 0.5
Calcium/Sodium Chloride
See Note 4
Less than 125 ppm
Less than 125 ppm
Less than 125 ppm
Chlorine
Less than 0.5 ppm
Less than 0.5 ppm
Less than 0.5
Hydrogen Sulfide
None Allowed
None Allowed
None Allowed
Biological
Growth
Iron Bacteria
None Allowed
None Allowed
None Allowed
Iron Oxide
Less than 1 ppm
Less than 1 ppm
Less than 1 ppm
Erosion
Suspended Solids - Note 5
Less than 10 ppm
Less than 10 ppm
Less than 10 ppm
Water Velocity
Less than 8 ft/s
Less than 12 ft/s
Less than 12ft/s
N
OTES
:
1. H
ARDNESS
IN
PPM
IS
EQUIVALENT
TO
HARDNESS
IN
MG
/
L
2. G
RAINS
/
GALLON
=
PPM
DIVIDED
BY
17.1
3. C
OPPER
AND
C
UPRO
-
NICKEL
HEAT
EXCHANGERS
ARE
NOT
RECOMMENDED
FOR
POOL
APPLICATIONS
FOR
WATER
OUTSIDE
THE
RANGE
OF
THE
TABLE
. S
ECONDARY
HEAT
EXCHANGERS
ARE
REQUIRED
FOR
APPLICATIONS
NOT
MEETING
THE
REQUIREMENTS
SHOWN
ABOVE
.
4. S
ALTWATER
APPLICATIONS
(
APPROX
... 25,000
PPM
)
REQUIRE
SECONDARY
HEAT
EXCHANGERS
DUE
TO
COPPER
PIPING
BETWEEN
THE
HEAT
EXCHANGER
AND
THE
UNIT
FITTINGS
. 5. F
ILTER
FOR
MAXIMUM
OF
600
MICRON
SIZE
.
5. Filter for maximum of 600 micron size.
Section 6: Unit Piping Installation