Page: 20
EnergyTech 401
CODEL
Operating and Maintenance Manual
Monitoring Solutions
V
=
22.4 (standard volume of an ideal gas)
The conversion factors for the analysers are given below :
CO
Molecular mass (RMM) = 12 + 16 =
28
1 vpm
=
28/22.4 =
1.25
mg/m
3
SO
2
Molecular mass (RMM) = 32 + 16 + 16
=
64
1 vpm
=
64/22.4 =
2.86 mg/m
3
NO
Molecular mass (RMM) = 14 + 16 + 16
=
46
(equivalent)
1 vpm
=
46/22.4 =
2.05 mg/m
3
Legislation demands that all oxides of nitrogen be expressed as NO
2
equivalent.
It is not necessary to measure both NO and NO
2
as the relationship is fixed in
particular processes, and typically is 95% NO; 5% NO
2
.
NO
x
1vpm
=
2.05 x (100%/NO%)
mg/m
3
The mass concentration present is calculated as below;
mg/m
3
(STP) = N. vpm
This value is the mass concentration of the gas at STP.
Finally the effects of water vapour and oxygen need to be considered.
Since the vpm measurement is already normalised for temperature and pressure,
the only further normalisation required is for the dilution effects of water vapour
and oxygen. These are straightforward calculations as shown below;
mg/Nm
3
= mg/m
3
(STP) x
20.9 - 0%
2
standard
x
100
20.9 - (0%
2
measured) DRY
100 - H
2
O%
Conversion factors (N)
2.2.4.3
Correction for oxygen
2.2.4.4
& water vapour
Содержание Energy Tech 401
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