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7010 TOC ANALYZER USER MANUAL

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SODIUM PERSULFATE

CLEANING

ACID

SAMPLE

TOC FLOW DIAGRAM

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Summary of Contents for 7010 TOC

Page 1: ...7010 TOC ANALYZER USER MANUAL 1 Version 1 12 Prepared DC Verified FG Checked FS Approved DM Issued 28 09 2015 ...

Page 2: ...2 Operating precautions and hazards 1 6 3 Chemical and waste gas hazards 2 INTRODUCTION 2 1 Analyzer description 2 2 Applications 2 3 Fast Loop Reservoir 2 4 Liquid enclosure components 2 4 1 Peristaltic pumps 2 4 2 Scrubber 2 4 3 UV reactor UVR UV Scrubber 2 4 4 U Tube 2 4 5 Glass condenser 2 4 6 Dryer 2 4 7 By pass Valve 2 5 Electrical enclosure components 2 5 1 Copper filter 2 5 2 Sodalime filt...

Page 3: ...ng 3 2 Location and mounting instruction 3 3 PRECOMMISSIONING 3 4 Electrical connections 3 4 1 AC Power connections 3 4 2 Analog output connections 3 4 4 Relay A B 3 4 5 Digital input output 3 4 6 Levels 3 4 7 External dilutor supply 3 4 8 Fuses 4 USER INTERFACE 4 0 User instructions 4 1 Main Page 4 2 Main page process values 4 3 Calibration page 27 28 28 29 29 30 31 31 31 32 33 34 34 35 36 37 37 ...

Page 4: ... 4 UVR tubing s connection replacement 5 5 UV lamps replacements 5 6 Fuses replacement 6 PREPARATION OF THE CHEMICALS 6 1 Preparation of the TOC standard solution 6 2 Preparation of the COD standard solution 6 3 Preparation of the Persulphate solution 6 4 Preparation of the Acid solution 6 5 Preparation of reducing solution 6 6 Preparation of the Cleaning solution 6 7 Preparation of TC Reagent sol...

Page 5: ...5 5 ...

Page 6: ...ad through and fully understand this instruction manual to ensure proper operation Pay attention to all caution and dangers labels present on the analyzer and all caution and danger statements written in this manual For analyzer installation and use please refer carefully to all information and recommendations present in this manual Failure to do so and non observance of hazard or danger warnings ...

Page 7: ...otential dangers The table below is a list of hazard and danger warning labels that is possible to find on the analyzer and or in this manual In the case of these labels becoming damaged or unreadable they should be replaced with new ones by the analyzer owner ...

Page 8: ...and dangers Before to proceed with the handling of chemicals or operations read the material safety data sheets supplied with each chemical to ensure all the necessary precautions are taken Concerned parts UV lamps Warning of general hazard This symbol means that is necessary read this manual before proceeding with any service operation to know exactly how to operate in a proper way Only qualified...

Page 9: ...It is necessary to connect an extension tubing or to provide for safe venting to the atmosphere or to a classified safe area 1 4 Sample Take appropriate precautions to avoid direct contact with sample stream It is responsability of the user to be aware of and take all precautions regarding physical chemical radiation and or biological hazards and dangers coming from sample stream and or sample vap...

Page 10: ...electrical device is necessary to interrupt the power line using a circuit breaker or an isolating switch to be sure that there is no power in the area being serviced Users and qualified maintenance personnels must proceed as follows pay attention to electrical shock and or electrocutions labels placed on the analyser always isolate power before servicing the analyser In case of loss of power the ...

Page 11: ...void risks the analyser s parts that become very hot to the touch have been designed built and located in closed enclosure with a special opening key When present inside the enclosures these parts have protection covers and warning labels to avoid any contact and physical injury to users Hazard of poisoning caused by waste gas coming out from VENT line Install the analyser in location of adequate ...

Page 12: ... built and located in a closed enclosure with a special opening key When present inside the enclosures these parts have protection covers and warning labels to avoid any contact and serious injury or death to users HAZARD PREVENTIVE ACTIONS HAZARD PREVENTIVE ACTIONS 1 6 3 Chemical and waste gas hazards The analyser has been designed built and equipped to avoid risks caused by physical and chemical...

Page 13: ...in liquid samples using the EPA approved method based on UV persulfate oxidation and detection of generated carbon dioxide using a Non Dispersive Infrared analyser This method meets also the requirements of European ISO CEN guidelines The analyser provides this measurements on liquid samples ranging from 0 5 mg l to 0 20000 mg l The analyser conforms to EPA DIN CE ASTM and NAMUR regulations 2 0 AN...

Page 14: ... has been designed for the following applications Industrial waste water Condensate and cooling water Drinking and river water Industrial water treatment plant inlet outlet For different applications or different aqueous matrices it is recommended to contact your Metrohm distributor to verify your application with our specialists ...

Page 15: ... the carrier gas generation and flow adjustment devices the controlleing PCB assembly and the infrared detector legend 01 UV lamp power supplies 02 glass condenser 03 by pass valve 04 condenser fan 05 dryer tubing 06 UV reactor 07 resample pump 08 sample pump 09 persulfate pump 10 phosphoric acid pump 11 auto pump 12 UV scrubber 13 U tube 14 scrubber 15 drain legend 01 user connections 02 copper f...

Page 16: ...ing carbon dioxide goes to the infrared analyser 13 passing in sequence through a glass condenser 02 gas drier tubing 05 and a halogens filter 02 These devices are present to prevent condensation and corrosion inside the stainless cell of the IR The carrier gas used for the oxidation and detection stages is generated by a second internal air compressor 09 and is passed through a sodalime filter 05...

Page 17: ...7010 TOC ANALYZER USER MANUAL 17 SODIUM PERSULFATE CLEANING ACID SAMPLE TOC FLOW DIAGRAM ...

Page 18: ...G REAGENT FLOW DIAGRAM legend 01 UV lamp power supplies 02 glass condenser 03 by pass valve 04 condenser fan 05 dryer tubing 06 UV reactor 07 resample pump 08 sample pump 09 persulfate pump 10 phosphoric acid pump 11 auto pump 12 UV scrubber 13 U tube 14 scrubber 15 drain X2 reducing reagent pump ...

Page 19: ...to the terminals that are found at the left hand side of the analyzer For a dual stream analyzer where dilution water is also required for one or both streams the third level switch is connected to the user connection inside the analyzer see page 37 For a single stream analyzer in the event of a missing sample or dilution water stream for a period longer than a preset time normally set on installa...

Page 20: ...7010 TOC ANALYZER USER MANUAL 20 LIQUID ENCLOSURE ...

Page 21: ...ove the inorganic carbon IC by gas sparging The resample pump head 07 is driven by the M1 motor and is located in the upper position UV lamps side It pumps the acidified and sparged sample from the bottom of the scrubber 14 to the T connection where it mixes with the carrier gas coming from the air compressor 09 and directed to UV reactor 06 The persulfate pump head 09 is driver by the M2 motor an...

Page 22: ...ed from the sample through the vent drain tubing connected to the straight upper position of the scrubber As a result the sample at the scrubber bottom is IC free and it can be pumped by resample pump 07 to the oxidation stage The UV reactor 06 is located on the left side of liquids enclosure It consists of two high energy UV lamps The reaction of oxidation is catalyzed by UV radiation with decomp...

Page 23: ...so drains the exausted sample and vents the sparging gas coming from the top of the scrubber The gas mixture coming from the oxidation stage is driven by the carrier gas to the drying devices through the upper right outlet of the gas liquid separator towards to the glass condenser 02 The Glass condenser 02 is positioned between U tube and the by pass valve The glass condenser uses the temperature ...

Page 24: ...xternal tubing In the external tubing there is a counter current purge gas flow that removes the water vapour The dryer prevents water condensation inside the IR cell CAUTION do not overtighten or twist gas dryer ends when installing or servicing as this will restrict the airflow The By pass valve shown in the diagram as 03 is activated during conditioning and cleaning phases It vents the gas stre...

Page 25: ...7010 TOC ANALYZER USER MANUAL 25 ELECTRICAL ENCLOSURE ...

Page 26: ... dryer tubing is forced to go through this device to prevent corrosive effects due to gases like chlorine or chlorine dioxide that could be generated in the oxidation stage The sodalime filter 05 is located on the left side of electrical enclosure It s a plastic container full of sodalime and it absorbs the carbon dioxide from atmospheric air providing the analyzer with CO2 free air for its proces...

Page 27: ...e They drive multiple pump heads that move the sample and reagents through the different analyser treatment stages Depending on the configurations there will be from three to six pump heads M1 05 06 rpm upper sample resample M2 1 rpm middle acid persulfate optional reducing reagent M3 10 12 rpm lower calibration validation cleaning 14 0 21 16 0 8 15 1 7 24 2 8 Pump Head mL rotation ...

Page 28: ...ressor 09 provides the carrier gas for oxidation and detection stages They eliminate the need for an external air treatment system and for compressed air as a requested utility this saving cost These devices 04 and 07 are located in the central part of the electrical enclosure with a pressure gauge on the front and are used to they allow for a highly precise and reliable adjustment for the carrier...

Page 29: ...cell It s a Non Dispensive Infrared analyser NDIR with high stability and reliability The measuring scale of IR is related to the range of 7010 TOC 7010 TOC analyzer provides 1 4 20 mA output A01 A second 4 20 mA output A02 is available on dual channels analyzers 2 relays RELAY A programmable and RELAY B fault 1 24 Vdc 1 digital input 1 digital output 1 level 3 additional contact RS485 2 5 7 USER ...

Page 30: ...7010 TOC ANALYZER USER MANUAL 30 INSTALLATION ...

Page 31: ...he glass parts of liquids enclosure using an appropriate plastic syringe and tubing 3 2 LOCATION AND MOUNTING INSTRUCTION It is recommended to install the analyzer in a suitable position The location must be clean covered and properly enclosed to provide the analyser with good ventilation and low dust concentration Operating environmental conditions are temperature between 5 and 40 C at max 80 rel...

Page 32: ...analyzer should be 20 cm on either side and 100 cm on the front Sufficient space for two 10 liter containers and one 5 liter container should be provided beneath the analyzer if necessary the reagents containers should be positioned in a suitable receptacle in case of spills Dedicated waste gas line should be provided for safe venting to the atmosphere unless installed in a well ventiled area of a...

Page 33: ...will receive the special key to open the electrical enclosure A circuit breaker must be installed near the analyzer to allow easy isolation of power in case of electrical problems and every time it is necessary to service the analyzer It will be user s task to check and guarantee periodically the perfect functionality of the analyzer s grounding To avoid potential fatal electrical shock and or ana...

Page 34: ...SER CONNECTIONS AC power enters on the top side of the electrical compartments through the supplied power cord All the connections must be made in accordance with national or local regulations It is recommended that the analyzer has its own dedicated circuit with a circuit breaker or an isolating switch installed near the unit 3 4 2 ANALOG OUTPUT CONNECTIONS The 7010 TOC analyzer provides 2 optica...

Page 35: ...s of sample alarm result alarm relay activated in case of result higher than the programmed value validation alarm relay activated in case of validation alarm reagent alarm relay activated in case of reagent s alarm calibration alarm relay activated in case of calibration alarm RELAY B is activated in case of fault alarm Fault alarms occur if certain conditions arise that risk the analyzer giving ...

Page 36: ...ity E Stop bit 1 PROTOCOL Slave I D 1 VALUES Address format alias 150 32 bits float CD AB result CH1 152 32 bits float CD AB result CH2 154 16 bit unsigned analyser status STATUS VALUES Stand by 0 Conditioning to drain 3 Conditioning purge detector 4 Online 5 Zerogas 6 Zerogas 7 Auto Function 1 Stopped 8 3 4 4 RS 485 ...

Page 37: ...conds the pause period is configurable between 1 and 999 minutes 3 4 6 LEVELS Level switch terminals level 1 and level 2 works with same logic as level switches left side connectors Additional level 3 can be configured with jumpers in order to be associated to 1 2 or 1 2 C is the common terminal 3 4 7 EXTERNAL DILUTOR SUPPLY 230 115 Vac for supplying power to the external dilutor Functions when th...

Page 38: ... red label in the phosphoric acid container beneath the analyzer and check that it is correct by position at the bottom of the container Put the persulfate inlet tubing white label in the sodium persulfate container beneath the analyzer and checkthat it is correct by position at the bottom of the container Put the cleaning or calibration or validation solution inlet tubing green label in the clean...

Page 39: ...ng waste with no restriction of gas liquid separator drain outlet The drain tube must not be submerged and the exhausted sample must be carried out by gravity It is not recommended to proceed with a zerogas cycle and a calibration cycle before leaving the analyzer in online status for 4 6 hours This selection depends on the user s sample composition and characteristics For dirty samples it is high...

Page 40: ...40 USER INTERFACE ...

Page 41: ...ists of a touchscreen located on the front panel of the analyzer enclosure All the output input data information alarms and fault conditions are shown on the display while all the commands and settings may be entered into to the analyzer simply by pressing the touchscreen buttons ...

Page 42: ...er to online operations or to stop the analyzer in stand by condition Stopped button displays the status of the analyzer when it is stopped reading only it is possible to escape from Stopped pressing Online or Standby buttons min pres 2 secs The trend of analysis It displays graphically the analyzer s value trend during time The name of the analysis for example TOC TC COD read only The value of an...

Page 43: ... the central result graph In the notepad data from the current day is shown In the case of an alarm being generated by the analyzer details will appear as a moving message at the bottom of the screen The message will identify the type of the alarm and the time the alarm was activated The message remains visible until the cause has been resolved ...

Page 44: ...E Pressing on the user can enter the 4 number passwords BASIC ADVANCED password 1111 access to calibration timing and datalogger pages SERVICE Pressing on password available from Metrohm Applikon technicians distributors access to calibration timing pages general setup pages and datalogger ...

Page 45: ...vation and programmation CARRIER flow displays the carrier gas flow value through the digital flowmeter in cc min CO2 conc displays the carbon dioxide value in ppm detected by the infrared analyzer VALIDATION displays the value of last validation against the last stored calibration value in percentage REAGENT TANKS LEVEL allows to reset the counter to 100 This operation should be done when the rea...

Page 46: ... carrier gas ambient air filtered by sodalime filter as detected by the infrared analyzer ppm liq zero the CO2 concentration value expressed in ppm generated by reagents and distilled water as detected by the infrared analyzer ppm baseline ppm zerogas ppm liq zero mg l standard displays the value in mg l of the standard solution used for calibration ppm span gas the CO2 concentration value express...

Page 47: ...concentration value expressed in ppm detected by the infrared analyzer decreases so that after the programmed delay time it will be stable and equal to the CO2 generated by carrier gas only This value is stored and shown as ZEROGAS A graphic of the trend of the ppm of CO2 value detected by the NDIR is shown together with a counter of the seconds programmed for the zerogas cycle the value of ppm of...

Page 48: ...of the sample pump from the external fast loop reservoir and connecting it to a distilled water container using an extension tube if necessary With these conditions the distilled water is pumped through all the fluidics until the operator decides that the CO2 concentration value expressed in ppm detected by the infrared analyzer is stable Press LIQUID ZERO button Wait for at least 30 minutes for a...

Page 49: ...on by pressing the standard number is it possible to set the value in mg l of the standard solution used for calibration With these conditions the standard solution is pumped through all the fluidics Once the operator decides that the CO2 concentration value expressed in ppm as detected by the infrared analyzer and the Value expressed in mg l is stable press the PRESS TO CAL button for few seconds...

Page 50: ...tions the standard solution is pumped from a container placed beneath the analyzer through all the fluidics for the number of minutes programmed on timing menu The CO2 concentration value expressed in ppm detected by the infrared analyzer will increases until after the programmed delay time when it will be stable and equal to the CO2 generated by the applied standard solution After subtracting the...

Page 51: ...ilable on the terminal of the user connections COND delay min Allows to set the number of minutes that analyzer reconditions with sample before on line operation after an autocal val clean or when switched on after a standby or a stop ZGas period sec Allows to set the number of seconds that zerogas cycle is active before storing the CO2 ppm value corresponding to zerogas Clean autocal autoval auto...

Page 52: ...nge of the analogue output Factor factor to be applied if dilution is used and or as a conversion factor to report results as another parameter i e COD OUTPUTS Relay A allows to set the function of the relay A ONLINE OFFLINE LOSS OF SAMPLE RESULT ALARM VALID ALARM REAG ALARM CALIB ERROR Relay B FAULT only read window 4 20 mA TEST allows to test the 4 20 mA output Using the switch it is possible to...

Page 53: ...n the door of the electronic enclosure and insert a USB key into the port that is positioned on the cover behind the door Go to the data logger menu violet USB logo and press on the button keeping it pressed until the software automatically exits back to the main screen On the USB key there will now be a folder named datalog inside which there is another folder named TOC where you will find one cs...

Page 54: ...7010 TOC ANALYZER USER MANUAL 54 4 7 ALARM LOG PAGE Service password Press Press to go to MAIN PAGE Press TIME Alarm occurring time EVENT kind ofalarm RESET TIME time when the alarm resets ...

Page 55: ...gth of time each stream will be measured A conditioning period as set in the Timings page will take place between each change of stream On the Settings page there is the possibility to set two different full scale values for the two analogue outputs In addition two independent Factor settings for each stream can be entered for correct calculation according to the dilution used or as a conversion f...

Page 56: ...xceeds the programmed threshold the analyser will switch from range L low to range H high and the extra relay will be activated Every time the analyzer is turned ONLINE or after an OFF LINE operation ZERO GAS AUTOFUNCTION LOSS OF SAMPLE it starts from the high range condition diluted sample A conditioning period will divide the two statuses during which no results will be displayed ...

Page 57: ...UAL 57 When the DUAL RANGE option is selected the TIMING PAGE allows to set the thresholds where the instrument will switch between high and low ranges After the conditioning period the result according to range H high is shown ...

Page 58: ... the analog output referring to the current range is active while the other is forced down to 0 4 mA External dilution factor determines the range H high result calculation The A relay can be used to report the range L low or H high status ...

Page 59: ...7010 TOC ANALYZER USER MANUAL 59 MAINTENANCE ...

Page 60: ...Enclosure Visual check of halogens filter Visually inspect the scrubber and UV scrubber for normal bubble flow Sample fast loop reservoir cleaning Refill reagent containers Scrubber and gas liquid separator cleaning Soda lime replacement in soda lime filter Copper wool replacement in halogens filter Pumps tubing replacement UV lamps check for leakages and tubing connection replacement Maintenance ...

Page 61: ...uids Enclosure D Disconnect each pump tubing from their inlet and outlet fittings taking care to note which fitting will be needed to reconnect to which pump E Undo the four wings nuts on the mounting screws that supports pump heads F Slide the pump heads to left and remove them from the mounting screws G Carefully separate the two halves avoiding dropping the rotor and then removing the used tubi...

Page 62: ...th a screwdriver until the shaft aligns with the motor drive L Replace the four wing nuts tightening them to finger tight so to have a firm mounting of the pump head M Repeat the steps from D to L for each additional pump head for which it is necessary to replace the tubing N Reconnect the acid and persulfate intake tubing to their containers run online the analyser O The analyser will start the c...

Page 63: ... the analyser in stand by and open the analyzer electrical enclosure B disconnect the inlet and outlet tubing of the filter from their fittings C remove the filter plastic body from its support clamp D unscrew top and bottom caps from filter body E with extreme care using a proper tool pull out the used wool from ther plastic cylinder F replace the used wool with new wool and press it into place t...

Page 64: ... in an adequate environment Before to proceed to sodalime replacement in sodalime filter read with care the material safety data sheets supplied with this chemical to take all the necessary precautions when handling Used sodalime must be disposed according with national or local environmental regulations regarding hazardous and poisonous materials A put the analyser in stand by and open the analyz...

Page 65: ...of the UV lamps taking care not to impede the liquid flow see adjacent diagram F The norprene tubing should cover the Teflon tubing and the arm of the quartz inlets outlets of the UV lamps G Use the black clamps supplied to fix the norprene tubing to the Teflon tubing H Check the clamp has been correctly positioned that there are no leakages using a syringe with DI water connected at the same poin...

Page 66: ...e the wires from the cable guide in the top of the Liquid Enclosure E Disconnect the UV lamp wires from the rear of the UV lamp power supplies after first cutting the gain protecting the connection F Remove the four screws supporting the lamps using a 3 mm Allen key or driver G Cut the black clamp holding the tubing to the top and bottom of the lamps H Connect the replacement lamps to the UV lamp ...

Page 67: ...perience to avoid electricity hazards and dangers The 7010 TOC analyzer has two fuses located inside the USER CONNECTIONS labelled as F1 and F2 Before to proceed to service operations on the electrical enclosure read carefully all the information written in this manual regarding this matter To avoid any risk turn off the analyzer main power before servicing the electrical enclosure A turn off main...

Page 68: ...ange to calibrate or validate the TOC cleaning solution optional reducing reagent solution for applications with high content of chlorides Before to proceed to these solutions preparation read the material safety data sheets supplied with each chemical to take all the necessary precautions when handling Chemicals must be handled by qualified personnel trained on hazards and dangers to avoid accide...

Page 69: ...dling Always use suitable wears gloves and eyes protection For use of powdered chemicals wear a protective face mask or suitable respirator For standard solution preparation prepare a stock solution by adding the quantity shown in table 4 1 according to chosen compound and concentration in grams or ml into a 1000 ml class A volumetric flask Dilute to volume with reagent water If other concentratio...

Page 70: ...precautions when handling Always use suitable wears gloves and eyes protection For use of powdered chemicals wear a protective face mask or suitable respirator For 1000 mg l standard solution preparation prepare a stock solution by adding 0 85 g of potassium hydrogen phthalate KHP into a 1000 ml class A volumetric flask Dilute to volume with reagent water If other concentrations are required dilut...

Page 71: ... proceed to prepare the sodium persulfate solution read with attention its material safety data sheet and use all precautions recommended when handling Add 5 liters of distilled water in a 10 liters container that has been previously cleaned and flushed with distilled water Add 2380 g sodium persulfate and dilute to 10 liter volume with distilled water dissolving the powder by shaking Plug the con...

Page 72: ...mmended when handling IMPORTANT WARNING always add acid to water and never the reverse Take care for spills or skin contacts Add 8 liters of distilled water in a 10 liters container that has been previously cleaned and flushed with distilled water Add very slowly and with extreme care 1175 ml of 85 phosphoric acid and dilute to 10 liter volume with distilled water to have a 10 solution Plug the co...

Page 73: ... liters of distilled water in a 10 liter container that has been previously cleaned and flushed with distilled water Add 200 g hydroxylamine hydrochloride and dilute to 10 liter volume with distilled water Cap the container and dissolve the powder by agitating the container until the solution appears clear Consumption 10 L month for continuous operation 6 5 PREPARATION OF REDUCING SOLUTION ...

Page 74: ...e dirty Try to establish the best interval and duration of cleaning cycle to optimize the dirt removal from these points If necessary contact the Metrohm Applikon service department to have advice on this matter Always wear eyes gloves and clothes protection when handling Before to proceed to prepare cleaning solution read with attention its material safety data sheet and use all precautions recom...

Page 75: ... Wear suitable gloves face mask protective clothing and operate in an adequate environment Before to proceed to prepare the mixed solution read with attention the material safety data sheet and use all precautions recommended when handling Add 7 liters of distilled water in a 10 liters container that has been previously cleaned and flushed with distilled water Add very slowly and with extreme care...

Page 76: ...he analyzer running B Run the analyzer for at least 1 hour in these conditions C After 1 hour put the analyzer on Standby D Remove power from the analyzer by disconnecting the plug from the power line E Dispose of remaining reagent solutions and standards according to local regulations If the analyzer is to moved or shipped to a new location then all liquid should be removed beforehand A Proceed a...

Page 77: ...s of reagents restore sample flow check carrier gas line coming from air compressor 09 until UV reactor outlet tubing looking for blockages and or eventual failures check for pump delivery of standard solution and persulfate prepare a fresh standard solution and make a double check on its correct value verify that the infrared analyser is properly working replace sodalime in sodalime filter check ...

Page 78: ... Hz Power consumption MAX 350 VA for 115 Vac MAX 250VA for 230Vac Fuses 3 15 A 230V 4A 115V INSTALLATION REQUIREMENTS Mounting wall or support rack Environmental temperature 5 40 C 41 104 F Humidity 0 75 Cabinet cold rolled epoxy powder coated steel Dimensions 750 x 600 x220 mm Weight Kg 37 approximately depending on range configuration Reagents consumption 10 liters 28 days Analog outputs N 2 4 2...

Page 79: ...7010 TOC ANALYZER USER MANUAL 79 CLEANING TC REAGENT TOTAL CARBON TC FLOW DIAGRAM ...

Page 80: ...7010 TOC ANALYZER USER MANUAL 80 SODIUM PERSULFATE CLEANING ACID SAMPLE TOC FLOW DIAGRAM USING NITROGEN AS CARRIER GAS ...

Page 81: ...7010 TOC ANALYZER USER MANUAL 81 Metrohm Applikon BV DE BRAUWEG 13 3125 AE SCHIEDAM THE NETHERLANDS E mail info metrohm applikon com Tel 31 0 10 2983555 Fax 31 0 10 4379648 ...

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