M02
J40
M6-
04
WDAT-3
2.160-3.660
- R E S I D U AL R I S K S -
11
07 Manipulation
and
storage
Manipulation:
Technical measures/precautions
.
Form of storage and manipulation applicable to the products: PRESSURIZED GAS.
Ensure adequate ventilation and evacuation for the level of equipment.
Advice for use
: Prevent sparks and contact with hot surfaces. DO NOT SMOKE..
Storage:
Technical measures/Storage procedures
: Store at room temperature in the original container. Keep away from flames, hot
surfaces and sparks. Store in a cool, well-ventilated place. Protect full containers from sources of heat to avoid excessive
pressures.
Packing:
Recommended
: Ordinary steel, Stainless steel.
Avoid
: Alloy containing more than 2% magnesium.
Plastics.
08 Control
of
individual
exposure/protection
Precautionary measures to be taken
: Ensure a sufficient exchange of air and/or suction in workplaces.
Control parameters.
Exposure limits:
recommended by ELF ATOCHEM: VME = 1000ppm=4420mg/m
3
Individual protective equipment
:
Respiratory protection: In case of insufficient ventilation, carry suitable breathing apparatus.
Protection for the hands: Gloves
Protection for the eyes: Protective eyewear.
Specific hygiene measures: avoid contact with the skin, eyes and inhalation of the vapours. DO NOT SMOKE.
09 Physical
and
chemical properties
Physical state (20°C):
liquid gas
Colour:
colourless
Smell
: Slightly similar to ether; pH: not applicable.
Boiling point/interval
: -26,4°C
Melting point/interval
: -101°C
Flash point:
No flare up at test conditions
Self-ignition temperature:
743°C (1bar) 215°C (3bar)
Vapour pressure
: (25°C):0.665MPa (6.65bar) a (50°C):1.32MPa (13.2bar) a (70°C): 2.12MPa (21.2bar)
Vapour density:
(25°C): 4.26kg/m
3
Density:
(25°C):
1206kg/m
3
a (50°C): 1102kg/m
3
a (70°C): 996kg/m
3
Solubility:
water:
(25°C): 0,9g/l
Distribution coefficient:
log Pow = 1.06 (n-octanole/water)
Other data:
Henry constant: 1.53Pa m
3
/mol
Not dissociated in water
Solubility of water in the product at 25°C: 0,097% in weight.
Critical temperature: Tc=101°C
Critical pressure. Pc=4.07MPa (40.7bar)
10 Stability
and
reactivity
Conditions to avoid: Avoid
contact with flames and red-hot metal surfaces.
Dangerous decomposition products
: Thermal decomposition into toxic and corrosive products: hydrofluoric acid,
hydrochloric acid in gaseous form, phosgene, carbon monoxide (CO)
Other information
: Stable product at ambient temperature.
In presence of air the product can mix up into a flammable blend at particular temperature and pressure conditions.
11 Toxicological
information
Acute toxicity:
Inhalation
: Practically non-toxic in experiments conducted on animals.
CL50/inhalation/4 hrs/on rats>500000ppm
As with other volatile aliphatic halogenated compounds, with the accumulation of vapours and/or the inhalation of large
quantities, the product can cause: loss of consciousness and heart problems aggravated by stress and lack of oxygen; risk of
death.
Local effects:
Contact with skin
: Frostbite possible from splashes of liquefied gas.
Practically non-irritating for skin in experiments conducted on animals (rabbits).
Contact with the eyes:
practically non-irritating for eyes in experiments conducted on animals (rabbits).
Sensibilisation:
Contact with skin: Experim,ental for the animal:
No skin sensitizer (guinea pig).
Chronic toxicity:
Studies on animal protracted inhalation do not highlight any chronic toxic effect (rat/ years(s)/ Inhalation:
50000ppm)
Specifical effects:
Genotoxicity according experimental available data NOT Genotoxic
Cancerogenesis
: experiments on animals do not highlight carcinogen effect clearly demonstrated (rat /Inhalation – for oral
administration)
Toxicity for reproduction:
Foetal growth no toxic effect for foetal development (rat/rabbit/inhalation).
Fertility, according the available data on animal: no toxic effects on fertility (rats/inhalation)
This document refers to the product as is and which conforms to the specifications supplied by ELF ATOCHEM.
If combinations or mixtures are made, check that there are no new dangers resulting from this action. The information provided in this
report has been provided in good faith and is based on our latest knowledge of the product in question as of the date of publication of
the same. The attention of users is drawn to the potential risks of employing the product for any use other than that for which it is
intended. This report must be used and reproduced solely for purposes of prevention and safety. The list of legislative, regulatory or
administrative texts must not be considered exhaustive. The product user is under obligation to refer to all the official texts concerning
the use, conservation and manipulation of the product for which he is sole responsible. The product user must also provide all those
who might come into contact with the product with the information necessary for their safety at work and the protection of their health
and that of the environment, giving them a copy of this safety information report.
Summary of Contents for WDAT-3 2.160
Page 2: ......