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D-31   June 2002

9

The conditions under which microfilm is stored 
have been found to play an important role in 
the development of microscopic blemishes. 
Storage in cool, dry air that is free of oxidizing 
gases or vapors is an effective means for 
arresting their formation and growth. Storage 
in sealed, metal cans is a sound preventive 
measure, if this is practical and consistent with 
the humidity requirements.

Additional protection can be obtained by adding 
molecular sieves to the storage containers 
or toning the film with toners such as Kodak 
Brown Toner (CAT No. 146-4452—8 oz.; 
CAT No. 140-0928—1 gal.). For information 
about the use of brown toner as a treatment 
to extend the life of microfilm, order Kodak 
Publication A-1671.

26

Toning

The life expectancy of your microfilm, processed 
to established quality control standards and stored 
under ideal environmental conditions, can be 
many years. However, we do not have control of 
environmental surroundings at all times.

Therefore, you should consider taking the extra 
precaution of toning your films against oxidative 
attack. Toning can be accomplished by use of 
sulfide toning agents such as Kodak Brown Toner. 
Other types of toners, such as selenium or gold, 
are also accepted but not commonly used. 
ANSI/PIMA IT 9.1-1998 (ISO 18901) now 
recognizes that films toned with toners like 
this can still be considered to meet the standards 
for records of permanent or long-term value. 
Brown toning is a service offered by the 
Kodak Disaster Recovery Laboratory. 
The lab can be reached at 1-800-EKC-TEST 
(1-800-352-8378) or 1-585-253-3907.

Chemical Contamination

Air contaminants may add an oxidizing or 
reducing effect to the atmosphere. This in turn 
may cause deterioration of the film base and a 
gradual fading of the photographic image, as 
well as the formation of the microscopic blemishes 
mentioned above. Typical contaminants are 
paint fumes, peroxides, nitrogen oxides, 
hydrogen sulfide, sulfur dioxide, and similar 
gases. If an area is to be painted, any films stored 
there should be removed beforehand and should 
not be returned to the area for three months. 
The removal of contaminating gases from the 
air requires special consideration.

5,14,15,16,17

Contaminants can come from illuminating gas, 
coal gas, automobile exhaust, and certain 
chemical plants. They are present in harmful 
concentrations in most industrial and urban areas. 
Other contamination can come from ozone and 
ammonia produced by certain photocopying 
devices. For this reason, a long-term storage vault 
should be located as far as possible from such 
areas. When a contaminated atmosphere cannot 
be avoided, steps should be taken either to 
eliminate the fumes by air conditioning the 
storage area or to protect the film from contact 
with the atmosphere by sealing it in containers.

In addition to atmospheric contaminants, care 
should be taken about other materials kept or 
used in the storage area. It has already been 
mentioned that nitrate-base films should never be 
used for permanent-record films. Furthermore, 
such films should never be stored with safety-film 
records (either in the same room or in rooms 
connected by ventilating ducts in the same 
building) because the gases given off by 
decomposing nitrate film will damage or destroy 
images on safety-film records.

Films not of the silver-gelatin type (e.g., diazo and 
vesicular) should not be wound on the same rolls, 
stored in the same containers, or be in physical 
contact with silver-gelatin films. In addition, some 
older vesicular films have been known to give off 
acidic fumes and require a separate storage 
housing with a separate circulating air system.

4

Avoid using rubber bands around rolls of film, 
since residual sulfur from rubber vulcanization 
promotes the growth of microscopic blemishes. 
Adhesive tapes, tape splices, bleached papers, 
and printing inks also cause undesirable effects.

Содержание D-31

Страница 1: ...Micrographic Quality D 31 Storage and Preservation of Microfilms ...

Страница 2: ...Low Humidity 5 Molecular Sieves 6 Humidity Control 7 Air Conditioning 7 Moisture Tight Containers 7 Humidification 8 Fungus Growth 8 Microscopic Blemishes 8 Toning 9 Chemical Contamination 9 Composition of Enclosure Materials 10 Paper 10 Plastic 10 Metal 10 Adhesive 10 Printing Inks 10 Theft Protection 10 Processing for Permanence 11 Silver Gelatin Films 11 Fixing Baths 11 Washing 11 Squeegees 12 ...

Страница 3: ...Nuclear Explosions 13 Time Capsule Storage 14 Handling and Filing Film Records 14 Interfiling 14 Inspection 15 Table 1 Applicable Standards for Microfilm 15 Table 2 Storage Life of Microfilms 16 Table 3 Storage Temperature and Relative Humidity 17 Summary of Requirements for Storage and Preservation of Records on Kodak Microfilm 17 Storage Facilities 17 References and Bibliography 18 ...

Страница 4: ...elatin thermally processed silver TPS diazo and vesicular films as they relate to film permanence It also describes the essential requirements of good processing and storage practices NOTE Refer to the latest revision of each ANSI or ISO Standard specified Definitions To help understand storage requirements the composition and structure of microfilm are described and definitions of commonly used t...

Страница 5: ...phthalic acid All safety films both acetate and polyester manufactured by Eastman Kodak Company meet these requirements This means that they are difficult to ignite and are slow burning All silver gelatin Kodak Microfilms on Estar Base when processed as recommended by Kodak meet the current specifications established by the American National Standards Institute Inc ANSI for films intended for use ...

Страница 6: ...e retrieved without significant loss when stored at 21 C and 50 RH For example LE 100 indicates that information can be retrieved for at least 100 years of storage Silver gelatin films have an LE of 500 thermally processed silver TPS have an LE of 100 years Extended term storage conditions storage conditions suitable for the preservation of recorded information on the majority of freshly processed...

Страница 7: ...h pressure to damage or explode the cabinet There is practically no danger of an explosion from the storage of either Estar Base or acetate base safety film under these conditions There are small amounts of organic materials in acetate film base as well as moisture which will expand under heat and under some conditions might generate slight pressure However such intense heat would be required on t...

Страница 8: ...ning in storage the humidity of the work area should not be markedly different from that of the storage area Very large humidity differences may lead to some physical distortion The best relative humidity for storage is the lowest that can be achieved practically and controlled reliably within the limits specified in ANSI PIMA IT9 11 1998 and ISO 189115 or their latest revisions High Humidity Stor...

Страница 9: ...otential film degradation agents such as moisture oxidants solvents and others when kept in close proximity with the films under confined storage 24 Therefore Eastman Kodak Company recommends the use of molecular sieves with triacetate and polyester based films to reduce the physical aging of films and increase the longevity of black and white images under confined storage It also prevents ferroty...

Страница 10: ...ckets is recommended as this is an efficient desiccant Chemically pure silica gel may also be used as a desiccant provided that filtration is used to remove particle layers larger than 0 3 micron See ANSI PIMA IT9 11 1998 and ISO 18911 19985 or their latest revisions Moisture Tight Containers If humidity control of the storage area is not possible the storage of film in moisture tight containers i...

Страница 11: ...ar or thermally processed silver films The Kodak Disaster Recovery Laboratory offers no charge evaluation of suspect microfilm and can be reached at 1 800 EKC TEST 1 800 352 8378 or 1 585 253 3907 Microscopic Blemishes Some processed silver gelatin microfilms in storage for two to twenty years have developed microscopically small colored spots or blemishes The fogged leader at the outside of the r...

Страница 12: ...shes mentioned above Typical contaminants are paint fumes peroxides nitrogen oxides hydrogen sulfide sulfur dioxide and similar gases If an area is to be painted any films stored there should be removed beforehand and should not be returned to the area for three months The removal of contaminating gases from the air requires special consideration 5 14 15 16 17 Contaminants can come from illuminati...

Страница 13: ...hic images can be damaged by adhesives incorporating impurities such as sulfur iron copper or other ingredients that might react with image silver or gelatin Pressure sensitive adhesives and ether linked products should be avoided Rubber based products such as rubber cement should not be used Not only might they contain harmful solvents or plasticizers but they might be compounded with photographi...

Страница 14: ...tion To make sure that there is enough time for the fixing reaction to be completed specific recommendations for each type of film should be followed Undeveloped silver halides are dissolved by the fixer as complex ions of silver and thiosulfate As the silver content of the fixer increases with processing the silver thiosulfate complex becomes increasingly difficult to wash from the film This can ...

Страница 15: ...not recommended for microfilm because some hypo eliminators contain oxidizing agents that can contribute to the formation of emulsion blisters and microscopic blemishes Residual Hypo Test The accepted criterion for adequate washing is the methylene blue method described in ANSI PIMA IT9 17 1998 19 IT9 17 1998 also describes the silver densitometric method which has been suggested by the Associatio...

Страница 16: ...ped methods for safeguarding vital records in the event of a war or a natural catastrophe Many keep their vital records in underground repositories located many miles from large metropolitan areas When microfilm is kept underground in caves mines tunnels subbasements or similar locations special care should be taken to make certain that there is adequate control of the relative humidity Film shoul...

Страница 17: ...n Do not wind different generic film types on the same roll or store them in the same container Diazo and silver gelatin microfilms should be stored separately before and after processing Diazonium salt gases emitted from Diazo microfilm pre and post process can be detrimental to silver gelatin microfilm Continual handling of film even under favorable conditions causes some wear but wear can be ac...

Страница 18: ... is any indication that film records are not keeping properly storage conditions should be improved and other protective treatments given the film Make copies of films that show signs of deterioration because deterioration once initiated is an irreversible process that may be restrained but not terminated by improving storage conditions Therefore extensive and frequent inspections should be made A...

Страница 19: ... per square meter 1 Not above 0 014 grams per square meter 1 No more than perceptible tint by spot stain test All Films Storage Conditions Temperature and Relative Humidity See Table 3 Air Conditioning Not necessary unless film records are subjected to frequent or sustained high humidity 3 Essential including slightly positive air pressure Air Purification Normal Must be free from airborne gases d...

Страница 20: ...considered suitable for black and white silver gelatin thermally processed silver diazo and vesicular Kodak Microfilms Table 3 Storage Temperature and Relative Humidity NOTE If the storage temperature is sufficiently low or if the air where the film is to be handled is quite moist leave the film in its closed container until it warms up to approximate room temperature Otherwise condensation of moi...

Страница 21: ...ment ASHRAE Handbook New York American Society of Heating Refrigerating and Air Conditioning Engineers 1992 17 HVAC Applications ASHRAE Handbook New York American Society of Heating Refrigerating and Air Conditioning Engineers 1991 18 Refrigeration ASHRAE Handbook New York American Society of Heating Refrigerating and Air Conditioning Engineers 1994 19 Recovering Silver from Photographic Materials...

Страница 22: ...ent Imaging Rochester New York 14650 www kodak com go docimaging Kodak Eastman Estar and Prostar are trademarks of Eastman Kodak Company KODAK Publication No D 31 CAT No 811 6386 6 2002 Eastman Kodak Company 2002 Printed in U S A ...

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