MATERIAL SAFETY DATA SHEET
Carbon Dioxide
(Fire Extinguishing Agent and Expellant)
Revision Date: February 9, 2012
Page 2 of 6
4.
FIRST AID MEASURES
Eyes
Immediately flood the eye with plenty of warm water for at least 15 minutes, holding the eye open. Obtain
medical attention if soreness or redness persists.
Skin
Gently warm affected areas. Obtain medical attention if blistering occurs or redness persists.
Ingestion
Ingestion is not considered a potential route of exposure.
Inhalation
Remove from exposure. If there is difficulty in breathing, give oxygen. Obtain medical attention immediately.
Advice to Physicians
In case of frostbite, place the frostbitten part in warm water. If warm water is not available or impractical to
use, wrap the affected parts gently in blankets. DO NOT USE HOT WATER.
5.
FIRE - FIGHTING MEASURES
Extinguishing Media
Carbon Dioxide is used as an extinguishing agent and therefore is not a problem when trying to control a
blaze. Use extinguishing agent appropriate to other materials involved. Keep containers and surroundings
cool with water spray as containers may rupture or burst in the heat of a fire.
Unusual Fire and Explosion Hazards
Containers may explode in heat of fire.
Protective Equipment for Fire-Fighting
Wear full protective clothing and self-contained breathing apparatus as appropriate for specific fire
conditions.
6.
ACCIDENTAL RELEASE MEASURES
Wear full protective clothing and self-contained breathing apparatus. Remove leaking cylinder to a safe
place. Ventilate the area. Vapors can accumulate in low areas. Leaks inside confined spaces may cause
suffocation as oxygen is displaced and should not be entered without a self-contained breathing apparatus.
7.
HANDLING AND STORAGE
Cylinders should be properly stored and secured to prevent falling or being knocked over. Do not drag, slide
or roll cylinders. Do not drop cylinders or permit them to strike against each other. Never apply flame or
localized heat directly to any part of the cylinder. Store away from sources of heat or ignition. Storage area
should be: - cool - dry - well ventilated - under cover - out of direct sunlight
8.
EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Standards
Occupational exposure limits are listed below, if they exist.
Carbon Dioxide
ACGIH TLV:
5000 ppm (9000 mg/m3) STEL: 30,000 ppm (54,000 mg/m3)
OSHA PEL
: 5000 ppm (9000 mg/m3)
Engineering Control Measures
Use with adequate ventilation. There should be local procedures for the selection, training, inspection and
maintenance of this equipment. When used in large volumes or odor becomes apparent, use local exhaust
ventilation.
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