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57
B. Tempco Variation
Most conductivity instruments use an approximation of the temperature
characteristics of solutions, perhaps even assuming a constant value.
The value for KCl is often quoted simply as 2%/°C. In fact, KCl tempco
varies with concentration and temperature in a non-linear fashion. Other
solutions have more variation still. The Ultrameter
III
uses corrections
that change with concentration and temperature instead of single
average values. See Chart 1.
C. An Example of 2 different solution selections and the
resulting compensation
How much error results from treating natural water as if it were KCl at
15°C?
A tap water solution should be compensated as 442
TM
with a tempco of
1.68 %/°C, where the KCl value used would be 1.90 %/°C.
Suppose a measurement at 15°C/59°F is 900 microsiemens of true
uncompensated conductivity.
Using a 442
TM
correction of 10 (degrees below 25) x 1.68% indicates the
solution is reading 16.8% low. For correction, dividing by (.832) yields
1082 microsiemens as a compensated reading.
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