![PP Systems TARGAS-1 Скачать руководство пользователя страница 158](http://html1.mh-extra.com/html/pp-systems/targas-1/targas-1_operation-manuals_1592671158.webp)
TARGAS-1 Operation Manual V. 1.02
158
𝑪𝑪𝑪𝑪
𝑪𝑪𝑻𝑻
=
𝒃𝒃
In this case the value of
𝑪𝑪𝑪𝑪
/
𝑪𝑪𝑻𝑻
is calculated from a linear regression of the C and T data.
Correction for water vapor increase on CO
2
efflux
In addition to the influx of CO
2
from soil, a closed chamber system can also experience an increase in
H
2
O due to evapotranspiration from soil or plants. This added H
2
O dilutes the remaining CO
2
and
requires a compensation in a similar way to equation
(A.13)
.
For total moles of air in the chamber of
𝑾𝑾
,
(2.7)
the moles of H
2
O added to the chamber is
𝑬𝑬
=
(
𝒆𝒆
𝒍𝒍𝒊𝒊𝒊𝒊𝒂𝒂𝒎𝒎
−𝒆𝒆
𝒊𝒊𝒊𝒊𝒊𝒊𝒐𝒐
)
(
𝟏𝟏𝟎𝟎𝟎𝟎𝟎𝟎−
𝒆𝒆
𝒍𝒍𝒊𝒊𝒊𝒊𝒂𝒂𝒎𝒎
)
,
where
𝒆𝒆
𝒊𝒊𝒊𝒊𝒊𝒊𝒐𝒐
and
𝒆𝒆
𝒍𝒍𝒊𝒊𝒊𝒊𝒂𝒂𝒎𝒎
are H
2
O concentrations in mmol mol
-1
.
The initial moles CO
2
in the system =
𝑪𝑪
𝒊𝒊𝒊𝒊𝒊𝒊𝒐𝒐
×
𝑾𝑾
, where
𝑪𝑪
𝒊𝒊𝒊𝒊𝒊𝒊𝒐𝒐
is CO
2
concentration in mol mol
-1
.
Then, the final moles CO
2
in the system =
𝑪𝑪
𝒍𝒍𝒊𝒊𝒊𝒊𝒂𝒂𝒎𝒎
× (
𝑾𝑾
+
𝑬𝑬
)
, where
𝑪𝑪
𝒍𝒍𝒊𝒊𝒊𝒊𝒂𝒂𝒎𝒎
is CO
2
concentration in mol mol
-
1
.
(2.8)
The change in moles of CO
2
is
(
𝑪𝑪
𝒍𝒍𝒊𝒊𝒊𝒊𝒂𝒂𝒎𝒎
× (
𝑾𝑾
+
𝑬𝑬
)
−
(
𝑪𝑪
𝒊𝒊𝒊𝒊𝒊𝒊𝒐𝒐
×
𝑾𝑾
) =
�𝑪𝑪
𝒍𝒍𝒊𝒊𝒊𝒊𝒂𝒂𝒎𝒎
− 𝑪𝑪
𝒊𝒊𝒊𝒊𝒊𝒊𝒐𝒐
�𝑾𝑾
+
𝑪𝑪
𝒍𝒍𝒊𝒊𝒊𝒊𝒂𝒂𝒎𝒎
𝑬𝑬
The term
�𝑪𝑪
𝒍𝒍𝒊𝒊𝒊𝒊𝒂𝒂𝒎𝒎
− 𝑪𝑪
𝒊𝒊𝒊𝒊𝒊𝒊𝒐𝒐
�𝑾𝑾
is equivalent to the
𝑪𝑪𝑪𝑪
/
𝑪𝑪𝑻𝑻
term calculated above, and the
𝑪𝑪
𝒍𝒍𝒊𝒊𝒊𝒊𝒂𝒂𝒎𝒎
𝑬𝑬
term is the
correction due to evapotranspiration.
(2.9)
So, with the H
2
O compensation, we have
𝑪𝑪𝑪𝑪
𝑪𝑪𝑻𝑻
=
𝒃𝒃
+
𝑪𝑪
𝒍𝒍𝒊𝒊𝒊𝒊𝒂𝒂𝒎𝒎
�
𝒆𝒆
𝒍𝒍𝒊𝒊𝒊𝒊𝒂𝒂𝒎𝒎
− 𝒆𝒆
𝒊𝒊𝒊𝒊𝒊𝒊𝒐𝒐
𝟏𝟏𝟎𝟎𝟎𝟎𝟎𝟎 −
𝒆𝒆
𝒍𝒍𝒊𝒊𝒊𝒊𝒂𝒂𝒎𝒎
�
where
𝒃𝒃
can be either from the quadratic or linear fit.
FCO
2
Units for measurement of Soil CO
2
Efflux
(2.10)
To give the CO
2
flux in mass/unit area/unit time the following conversion is made:
𝑭𝑭
𝑪𝑪𝑯𝑯𝟐𝟐
(g m
−2
hr
−1
) =
𝑪𝑪𝑪𝑪
𝑪𝑪𝑻𝑻
µ
mol
mol s ×
𝑷𝑷
1013 ×
273
273 +
𝑻𝑻
𝒂𝒂𝒊𝒊𝑯𝑯
×
44.009 g
22.414 L ×
𝑽𝑽
m
3
𝑨𝑨
m
2
×
mol
10
6
µ
mol ×
3600 s
hr ×
10
3
L
m
3
Where
𝑪𝑪𝑪𝑪
/
𝑪𝑪𝑻𝑻
is from eqn 1.9 from linear or quadratic fit and with H
2
O compensation
𝑷𝑷
𝟏𝟏𝟎𝟎𝟏𝟏𝟑𝟑
is the correction for barometric pressure with P measured in mbar by the TARGAS-1,