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100
1000
10000
100000
Approximate CO2 Concentration (ppm)
Bandbr
oadening Co
efficient f
or H
2O
1.5
1.4
1.3
1.2
1.1
1.0
Figure A-1. The typical relationship between
h
(
α
'
c
) and CO
2
concentration.
Note:
We formulated equation A-19 with 0.64
b
w
– 0.64 instead of the simple
equivalent (0.29) because this allows band broadening corrections to be turned
off by setting
b
w
to 1. When
b
w
=1,
h
(
α
c
) = 1 everywhere. Also, to avoid com-
putational problems (underflows, overflows, and division by zero) we constrain
the argument
α
c
when computing
h
(
α
c
) to be 0.1 <
α
c
≤
z
.
α
c
- 0.1 is typically
equivalent to about 600 ppm.
Calibration Equations
The following equations describe the implementation of zero and span calibrations.
Zeroing H
2
O (LI-850 only)
When the command for zeroing water is received, the LI-850 computes the water
zero from equation A-20, where
and
are averaged for 5 seconds.
A-20
Zeroing CO
2
When the command for zeroing CO
2
is received, the instrument computes the
CO
2
zero term from equation A-21, where
,
,
, and
are averaged for
5 seconds.
Appendix A. Equation Summary
A-5
Appendix A. Equation Summary
Содержание LI-830
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