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14

A chloride electrode may be used as an indicator to follow
the progress of a chloride tiration with silver nitrate.  The
electrode can be used in colored samples where other
indicators suffer from interferences. During the titration the
sensor follows the decrease in chloride concentration while
small additions of silver nitate titrant are added. The silver
reacts with the chloride ions forming a precipitate of  silver
chloride.   At the stoichiometric end point, a large change in
mV occurs.   Measurements may be automated by use of
the Hanna Titrator HI 901 or titrated manually.

XIII.

XIII.

XIII.

XIII.

XIII.pH

pH

pH

pH

pH

The HI 4107 and HI 4007 electrodes  may be used in
solutions with pH values between 2 and 11.  Samples that
fall beyond this range should be adjusted with acetate pH
buffer. See Section VI.

Titration

Titration

Titration

Titration

Titration

XIV. S

XIV. S

XIV. S

XIV. S

XIV. Storage and Care of the HI 4007 and

torage and Care of the HI 4007 and

torage and Care of the HI 4007 and

torage and Care of the HI 4007 and

torage and Care of the HI 4007 and

         

         

         

         

         HI 4107 sensors

HI 4107 sensors

HI 4107 sensors

HI 4107 sensors

HI 4107 sensors

The HI 4007 sensor can be stored in very dilute standards
(<10

-4

 M) for short periods of time and should be stored

dry with the protective cap on when not in use.
The model HI 4107 combination electrode can be left in
dilute standards (<10

-4

 M) for short time periods.

For long term storage, the electrode should be drained and
washed of salts with distilled ot deionized water. Unscrew
the upper cap and move outer sleeve up cable.  Wrap the
ceramic junction on the inner stem with  Parafilm

®

 or

other sealing wrap. Place the protective cap provided over
the sensor membrane.  Store dry disassembled electrode in
storage box provided with electrode.

Содержание HI 4107

Страница 1: ...HI 4007 HI 4007 HI 4007 HI 4007 HI 4007 HI 4107 HI 4107 HI 4107 HI 4107 HI 4107 Chloride Ion Selective Electrode Instruction Manual CHLORIDE HI 4007 HI 410 COMBINATION 7 CHLORIDE Half cell Combinatio...

Страница 2: ...utions The HI 4007 is a solid state half cell sensor that requires a separate reference The HI 4107 is a combination ion selective electrode II II II II II Specifications Specifications Specifications...

Страница 3: ...asareferenceelectrode incorporated in its design The silver chloride pellet is prac tically insoluble in the test solutions being measured and producesapotentialchangeduetochangesinthesample s ion act...

Страница 4: ...4107 Design elements of the HI 4007 and HI 4107 Design elements of the HI 4007 and HI 4107 electrodes electrodes electrodes electrodes electrodes CHLORIDE HI 4007 Cap Sensing Membrane Sensor Handle U...

Страница 5: ...lutions Required Solutions Required for Chloride Measurements for Chloride Measurements for Chloride Measurements for Chloride Measurements for Chloride Measurements Select appropriate Hanna Instrumen...

Страница 6: ...libration standards and sample solutions should have the same ionic strength ISA acetate buffer or oxidizing reagent should be added to both samples and standards in the same ratio Calibration standar...

Страница 7: ...ing normal use fill solution will slowly drain out ofthetaperedconejunctionatthelowerportionofthe electrode Excessiveloss 4cmdropwithin24hours isnotnormal Ifthisoccursverifycapistightenedand the inter...

Страница 8: ...m seal found over ceramic junction on inner stem and discard This is only used for ship ping and long term storage 2 Rinseinnerstemwithdeionizedwatermakingcertain to wet the o ring found on the inner...

Страница 9: ...verify elec trodereturnstoitsoriginalposition Youmayneedto gently assist for this to occur 7 Tighten the electrode cap onto the body and fill elec trode body until fill solution volume is just below f...

Страница 10: ...action Corrective action Corrective action Corrective action Corrective action Verify protective cap has been removed HI 4007 Verify plastic film has been removed from inner stem HI4107 Verify electr...

Страница 11: ...he meter is calibrated with two or more freshly made stan dards that are in the linear measurement range of the unknowns Morecalibrationstandardsarerequiredinnon linear regions Unknowns are read direc...

Страница 12: ...ements using the oxidizing reagent must be made 10 minutes after mixing and not permitted react longer 3 Follow sectionVII GeneralGuidelinestooptimizetest set up 4 Duringcalibrationitisbesttostartwith...

Страница 13: ...mplifies the method greatly Example Chloride ion determination with known addition 1 A 50 mL sample of unknown Vsample is placed in a clean plastic beaker with a chloride sensor Add 2 mLofacetatepHbuf...

Страница 14: ...r See Section VI Titration Titration Titration Titration Titration XIV S XIV S XIV S XIV S XIV Storage and Care of the HI 4007 and torage and Care of the HI 4007 and torage and Care of the HI 4007 and...

Страница 15: ...s Conversion tables Conversion tables Conversion tables Conversion tables For Cl For Cl For Cl For Cl For Cl Multiply by Multiply by Multiply by Multiply by Multiply by Moles L M to ppm mg L 3 500x104...

Страница 16: ...6 monthsfromdateofpurchasewhenusedfortheirintended purpose and maintained according to instructions If they failtoworkwhenfirstusedcontactyourdealerimmediately Damageduetoaccidents misuse misapplicat...

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