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12

        Procedure
1) Follow  sections VIII and  IX  to prepare sensors for

measurement.

2) Follow  section VI to prepare standards/ solution.  Stan-

dards should bracket and fall within the range of
interest.
Two mL HI 4000-00 ISA, is added to 100 mL of both
samples and standards  Add stir bar and mix before
taking measurements.

3) Follow  section VII; General Guidelines to optimize test

set-up.

4) During calibration it is best to start with lower concen-

tration samples first.  Wait for a stable measurement
before recording values. Slightly longer equilibra-
tions are required at lower concentrations .

5) To prevent carry over and contamination of samples,

rinse sensors with DIW and dap dry between samples.

Typical Linearity for HI 4002 and HI 4102 Bromide 

sensors

-150

-100

-50

0

50

100

150

200

0

1

2

3

4

5

6

7

-Log of Molar Concentration

mV

Содержание HI 4102

Страница 1: ...1 HI 4002 HI 4002 HI 4002 HI 4002 HI 4002 HI 4102 HI 4102 HI 4102 HI 4102 HI 4102 Bromide Ion Selective Electrode Instruction Manual Half cell Combination BROMIDE HI 4002 HI 4102 BROMIDE COMBINATION...

Страница 2: ...ions in aqueous solutions The HI 4002 is a solid state half cell sensor that requires a separate reference The HI 4102 is a combination ion selective electrode II II II II II Specifications Specificat...

Страница 3: ...rolytic circuit The HI4102incorporates areferenceelectrode ThesilverBro mide pellet is practically insoluble in the test solutions being measured and produces a potential change due to changesinthesam...

Страница 4: ...I 4102 Design elements of the HI 4002 and HI 4102 Design elements of the HI 4002 and HI 4102 electrodes electrodes electrodes electrodes electrodes BROMIDE HI 4002 Cap Sensing Membrane Sensor Handle U...

Страница 5: ...romide Measurements for Bromide Measurements for Bromide Measurements for Bromide Measurements for Bromide Measurements 0 1 M Bromide Standard 500 mL HI4002 01 ISA 500 mL HI4000 00 ForMolarsolutions U...

Страница 6: ...ample from magnetic stirrer by placing cork or other insulative sheet between beaker and stirrer plate Calibration standards and sample solutions should be stirred at the same rate using identical siz...

Страница 7: ...e electrode with the fill hole open During normal use fill solution will slowly drain out ofthetaperedconejunctionatthelowerportionofthe electrode Excessiveloss 4cmdropwithin24hours isnotnormal Ifthis...

Страница 8: ...m seal found over ceramic junction on inner stem and discard This is only used for ship ping and long term storage 2 Rinseinnerstemwithdeionizedwatermakingcertain to wet the o ring found on the inner...

Страница 9: ...verify elec trodereturnstoitsoriginalposition Youmayneedto gently assist for this to occur 7 Tighten the electrode cap onto the body and fill elec trode body until fill solution volume is just below f...

Страница 10: ...rrective action Corrective action Verify protective cap has been removed HI 4002 Verify plastic film has been removed from inner stem HI4102 Verify electrodes are connected properly to meter and meter...

Страница 11: ...the unknowns Morecalibrationstandardsarerequiredinnon linear regions Unknowns are read directly At very low levels of bromide special precautions must be employed for reproducible measurements Water...

Страница 12: ...measurements 3 Follow sectionVII GeneralGuidelinestooptimizetest set up 4 Duringcalibrationitisbesttostartwithlowerconcen tration samples first Wait for a stable measurement before recording values Sl...

Страница 13: ...cause a mV change of at least 30 mV This method is preprogrammed in the Hanna HI 4222 pH ISE mV meter which simplifies the method greatly Example Bromideiondeterminationwithknownaddition 1 A 50 mL sam...

Страница 14: ...Titration Titration Titration Titration Titration XIV S XIV S XIV S XIV S XIV Storage and Care of the HI 4002 and torage and Care of the HI 4002 and torage and Care of the HI 4002 and torage and Care...

Страница 15: ...ersion T Conversion T Conversion T Conversion Tables ables ables ables ables For Br For Br For Br For Br For Br Multiply by Multiply by Multiply by Multiply by Multiply by Moles L M to ppm mg L 7 99x1...

Страница 16: ...6 monthsfromdateofpurchasewhenusedfortheirintended purpose and maintained according to instructions If they failtoworkwhenfirstusedcontactyourdealerimmediately Damageduetoaccidents misuse misapplicat...

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