background image

6

2  

Measurements

Check that the switch on the read-out unit is in the “

OFF

” position. Connect the signal cables from one, two or 

three Pt-electrodes to the BNC input connectors on the read-out unit, numbered 

1

2

 and 

3

, as appropriate. Pre-

pare a place in the soil for the reference electrode and the brass electrode. A distance of about 2 metres between 

these electrodes and the Pt-electrodes will usually be found satisfactory in the field, though it is by no means criti

-

cal. In horticulture a distance of a few centimetres may be chosen without any problem, depending on the size of 

the object. Connect a signal cable to the reference electrode. Bury the salt bridge and the brass electrode in the 
top layer of the soil. In dry soils, it is often necessary to water the soil to improve the electrical contact between 
these electrodes and the soil. Watering should be limited to the immediate vicinity of the salt bridge and the brass 
electrode. Its effect must never extend to the Pt-electrodes. Connect the signal cables from the reference electrode 
and the brass electrode to the corresponding inputs on the read-out unit. Allow 2 to 4 minutes for stabilisation.

2.1 

Measurement of Redox

The flow of an electric current in the soil disturbs the Redox equilibrium. Re-equilibration after 
an ODR measurement has been made may take between 15 minutes and several hours. So do 
not switch to ODR measurement before having done redox measurements.

When the switch on the read-out unit is turned from the “

OFF

” position to the “Redox” position the Redox poten-

tial between the soil and the Pt-electrode at input no 

1

 is displayed in mV. It takes some time when the electrodes 

have just been inserted into the soil before a steady reading can be obtained. This is often ten minutes, but in very 
dry soils it may rise to a few hours. Therefore we suggest to take a reading after ten minutes, wait for another ten 

minutes and take a second reading. When the difference is less than 20 mV, the latter reading can be taken as the 

equilibrium value.

In contrast to ODR electrodes, Redox electrodes can be left longer in the soil without any 
noticeable change of reading. After the first equilibration no further time-delays are required. 
It is important, though, that the part of the electrode structure that emerges from the soil is 
perfectly dry (no rain or dew) and does not move (stabilise against wind).

The Pt-electrodes as supplied with the ODR meter can very well be used as Redox electrodes. A simpler design is 
also feasible. In fact, a Pt wire or disc, mounted in an insulating rod and connected to a bare metal wire on top will 
do, provided that no slit is left between the platinum and the insulation where water could penetrate. With the 
read out unit in the 

Redox

 position and input no 

1

 connected to a cable that has a crocodile clip at its free end, the 

rapid measurement of a number of electrodes is possible.

2.2 

Measurement of ODR

Turn the switch on the read-out unit to positions 

1

2

 or 

3

 to read the ODR current at the corresponding elec-

trodes. The reading will rise to a high value and then continue to fall for some time, when the already dissolved 
oxygen is reduced. It takes several minutes for the ODR measurement to reach an equilibrium. Therefore we sug-
gest to take a reading after about three minutes, wait for another three minutes and take a second reading to see 
if an equilibrium has been reached yet.
Once the instrument is switched on, a current is maintained on all Pt-electrodes
connected to either input 

1

, input 

2

 or input 

3

. Of course, only one Pt-electrode, determined by the position of the 

switch is connected to the measuring circuit. The steady flow of a current implies, though, that subsequent meas

-

urements after the first one require less time, typically 20 seconds.

One millivolt in the display corresponds to a current of one microampere. The voltage shown on the display is also 
available as an analogue signal between contacts  and 5 of the output connector. To avoid an excessive current 
drain from the batteries, the input impedance of any indicating or recording instrument should not be less than 
ten kilo-ohms.

Содержание 14.36

Страница 1: ... ODR meter 3 1 3 Pt electrode 3 1 3 1 Preparation 3 1 3 2 Maintenance 4 1 4 Reference electrode 4 1 4 1 Commercial electrodes 4 1 4 2 Preparation for use 4 1 4 3 Maintenance 4 1 4 4 Storage 4 1 4 5 Preparation of a used electrode 5 1 4 5 1 Before re generating the electrode must be cleaned 5 1 4 5 2 Generating an Ag AgCl electrode 5 1 5 Brass electrode 5 1 5 1 Maintenance 5 2 Measurements 6 2 1 Me...

Страница 2: ...is a very complex system The results of an ODR measurement in a soil are highly sensitive to the voltage between the Pt electrode and the soil For comparable results the conditions of measurement should be well de fined and closely controlled The ODR meter has been designed to provide a stabilised voltage of 0 65 V between the Pt electrode and the Ag AgCI reference electrode and hence of 0 428 V b...

Страница 3: ...ltage At a voltage of about 0 5 volt between the Pt electrode and the soil the reduction of oxygen is the dominant process The magnitude of the cur rent will vary significantly with the voltage It is therefore important to specify the applied voltage and to keep the voltage within narrow tolerances during measurements The potential of the Pt electrode is measured with respect to an Ag AgCI referen...

Страница 4: ...trical connection a female BNC connector is provided at the top of the electrode assembly The electrode vessel is mounted in a screw cap that can be screwed onto a plastic bottle with a KCI solu tion A spare cap is provided to close the bottle when the electrode is in use The reference electrode and the salt bridge are depicted in figure 3 on page 11 1 4 1 Commercial electrodes Instead of the refe...

Страница 5: ...ter electrode will result in dis solvement of the Ag Doing this for a short period 30 seconds will clean the Ag electrode If necessarry the electrode can be de greased with aceton Always rinse with demi water 1 4 5 2 Generating an Ag AgCl electrode Method A After cleaning the Ag electrode is placed in a concentrated for example 5 FeCl3 solution The electrode stays in the solution for 10 minutes to...

Страница 6: ...0 mV the latter reading can be taken as the equilibrium value In contrast to ODR electrodes Redox electrodes can be left longer in the soil without any noticeable change of reading After the first equilibration no further time delays are required It is important though that the part of the electrode structure that emerges from the soil is perfectly dry no rain or dew and does not move stabilise ag...

Страница 7: ...ference electrode silver part head without body to middle pin connector resistance 1 ohm 5 Check Pt electrode point resistance to middle pin connector resistance 1 ohm 6 Check brass electrode to middle pin connector resistance 1ohm Check redox potential of electrodes Use a Zobell kalibration solution to check the electrodes for redox measurements The measurement value must be near the certified va...

Страница 8: ... few months When the instrument has to be transported over a long distance or will be stored for a long time the reference electrode is best emptied cleaned and dried When it is to be used again the procedure as described under 1 4 2 Preparation for use should be followed 4 Specifications Range Redox 0 to 999 mV ODR With the Pt probe surface area of 2 37 10 5 m2 0 0000237 m2 0 to 999 µA correspond...

Страница 9: ...mm exposed length 6 mm length 70cm Reference electrode Silver sheet 2 x 8 x 100 mm ceramic cup 100 ml PE plastic wide neck bottle probe provided with a pressure release screw Brass electrode Brass rod diameter 8 mm length 173 mm Literature An extensive discussion of the ins and outs of an ODR measurement has been given by D S McIntyre The plati num micro electrode method for soil aeration measurem...

Страница 10: ...10 Figure 1 Schematic diagram ...

Страница 11: ...ical data can be amended without prior notification Eijkelkamp Agrisearch Equipment is not responsible for personal damage due to improper use of the product Eijkelkamp Agrisearch Equipment is interested in your reactions and remarks about its products and operating instructions Reference electrode and salt bridge 1 BNC connector 2 Electrode head with silver electrode 3 Pressure realease screw 4 O...

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