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4

Drill a hole to the desired depth minus 0 mm and insert the electrode-rod into the hole. Exert a slight pressure on 
the top of the assembly to bring the electrode to its correct position. Take care not to damage the electrode. 

It is important that the electrode is positioned in undisturbed ground.

.3.2  Maintenance

Wipe the electrode clean with a soft tissue after use and replace the cover tube. In the rare case of very persistent 

stains, the use of the fibre pen will suffice. 

ODR electrodes should not be left in the soil for an extended period of time, since a decrease 
of readings may occur. It is best to take the electrodes out of the soil after the completion of 
one set of measurements and to reinsert them for the next one.

1.4 

Reference electrode

A silver-silverchloride electrode filled with a saturated KCI solution is used as the reference for voltage measure

-

ment. The Ag-AgCl electrode system is mounted on top of a porous, ceramic cup that is filled with a saturated KCI 

solution to serve as a salt bridge to the soil. The connection between the electrode system and the salt bridge is a 

wet junction. A minute flow of KCI solution from the electrode vessel into the salt bridge and from the salt bridge 

into the soil should always be maintained during measurements. The pressure release screw near the top of the 
electrode assembly should be left open whenever the electrode is in use. Only when not in use the pressure release 
screw may be closed. For the electrical connection a female BNC connector is provided at the top of the electrode 
assembly. The electrode vessel is mounted in a screw cap that can be screwed onto a plastic bottle with a KCI solu-
tion. A spare cap is provided to close the bottle when the electrode is in use. The reference electrode and the salt 

bridge are depicted in figure 3 on page 11.

.4.  Commercial electrodes

Instead of the reference electrode supplied with the instrument, a commercial Ag-AgCI electrode fitted with a 

salt bridge may be used. Though the procedure will not differ much from the one given above, always follow the 
instructions of the manufacturer.

.4.2  Preparation for use

Take the electrode assembly from the plastic bottle and close the bottle with the spare cap. Unscrew the pressure 
release screw one turn. Pull off the head of the silver electrode. Fill the vessel with a saturated solution of KCI to a 
level 5 mm below the brim. Check that the O-ring in the head is in good shape and replace the head.

.4.3  Maintenance

Refill the electrode vessel with a saturated KCI solution when the level has dropped about 30 mm below the initial 

level or if any signs of discolouration (poisoning) of the liquid is noticed. Keep the pressure release screw closed 
when the electrode is not in use to prevent unnecessary leakage of KCI. Brush the ceramic of the reference elec-
trode clean between and after use. Use a tooth brush and rinse ample water while doing this. 

.4.4  Storage

Always store the electrode/salt bridge assembly in its plastic bottle with KCI solution. See to it 
that the ceramic cup stays free from the bottom. The KCl solution in the storage bottle should 
be kept absolutely clean!

Содержание 14.36

Страница 1: ... ODR meter 3 1 3 Pt electrode 3 1 3 1 Preparation 3 1 3 2 Maintenance 4 1 4 Reference electrode 4 1 4 1 Commercial electrodes 4 1 4 2 Preparation for use 4 1 4 3 Maintenance 4 1 4 4 Storage 4 1 4 5 Preparation of a used electrode 5 1 4 5 1 Before re generating the electrode must be cleaned 5 1 4 5 2 Generating an Ag AgCl electrode 5 1 5 Brass electrode 5 1 5 1 Maintenance 5 2 Measurements 6 2 1 Me...

Страница 2: ...is a very complex system The results of an ODR measurement in a soil are highly sensitive to the voltage between the Pt electrode and the soil For comparable results the conditions of measurement should be well de fined and closely controlled The ODR meter has been designed to provide a stabilised voltage of 0 65 V between the Pt electrode and the Ag AgCI reference electrode and hence of 0 428 V b...

Страница 3: ...ltage At a voltage of about 0 5 volt between the Pt electrode and the soil the reduction of oxygen is the dominant process The magnitude of the cur rent will vary significantly with the voltage It is therefore important to specify the applied voltage and to keep the voltage within narrow tolerances during measurements The potential of the Pt electrode is measured with respect to an Ag AgCI referen...

Страница 4: ...trical connection a female BNC connector is provided at the top of the electrode assembly The electrode vessel is mounted in a screw cap that can be screwed onto a plastic bottle with a KCI solu tion A spare cap is provided to close the bottle when the electrode is in use The reference electrode and the salt bridge are depicted in figure 3 on page 11 1 4 1 Commercial electrodes Instead of the refe...

Страница 5: ...ter electrode will result in dis solvement of the Ag Doing this for a short period 30 seconds will clean the Ag electrode If necessarry the electrode can be de greased with aceton Always rinse with demi water 1 4 5 2 Generating an Ag AgCl electrode Method A After cleaning the Ag electrode is placed in a concentrated for example 5 FeCl3 solution The electrode stays in the solution for 10 minutes to...

Страница 6: ...0 mV the latter reading can be taken as the equilibrium value In contrast to ODR electrodes Redox electrodes can be left longer in the soil without any noticeable change of reading After the first equilibration no further time delays are required It is important though that the part of the electrode structure that emerges from the soil is perfectly dry no rain or dew and does not move stabilise ag...

Страница 7: ...ference electrode silver part head without body to middle pin connector resistance 1 ohm 5 Check Pt electrode point resistance to middle pin connector resistance 1 ohm 6 Check brass electrode to middle pin connector resistance 1ohm Check redox potential of electrodes Use a Zobell kalibration solution to check the electrodes for redox measurements The measurement value must be near the certified va...

Страница 8: ... few months When the instrument has to be transported over a long distance or will be stored for a long time the reference electrode is best emptied cleaned and dried When it is to be used again the procedure as described under 1 4 2 Preparation for use should be followed 4 Specifications Range Redox 0 to 999 mV ODR With the Pt probe surface area of 2 37 10 5 m2 0 0000237 m2 0 to 999 µA correspond...

Страница 9: ...mm exposed length 6 mm length 70cm Reference electrode Silver sheet 2 x 8 x 100 mm ceramic cup 100 ml PE plastic wide neck bottle probe provided with a pressure release screw Brass electrode Brass rod diameter 8 mm length 173 mm Literature An extensive discussion of the ins and outs of an ODR measurement has been given by D S McIntyre The plati num micro electrode method for soil aeration measurem...

Страница 10: ...10 Figure 1 Schematic diagram ...

Страница 11: ...ical data can be amended without prior notification Eijkelkamp Agrisearch Equipment is not responsible for personal damage due to improper use of the product Eijkelkamp Agrisearch Equipment is interested in your reactions and remarks about its products and operating instructions Reference electrode and salt bridge 1 BNC connector 2 Electrode head with silver electrode 3 Pressure realease screw 4 O...

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