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SAFETY DATA SHEET
SAFETY DATA SHEET
15
SAFETY DATA SHEET
SAFETY DATA SHEET
8. Exposure Controls
First Aid: Remove the affected person to fresh air. If breathing has stopped, administer artificial
DATE REVISED: 01.03.13
Take measures to prevent:
respiration. Give external cardiac massage if necessary. If the person is breathing, but unconscious,
Supersedes SDS dated N/A
Physical contact with liquid gas. Exposure to gas vapour in enclosed spaces.
place in the recovery position. Obtain medical assistance immediately.
Date issued: 01.03.13
Exposure Control Limits, and source:
Notes for Doctors: No special information.
THIS DATA SHEET HAS BEEN PREPARED IN ACCORDANCE WITH
Relevant only to unburned gases. The following exposure limits are taken from the health & Safety
12. Ecological Information
CRONER'S HAZARD INFORMATION AND PACKAGING GUIDE
Executive Guidance Note EH40/2005 Workplace exposure limits.
Possible effects:
Workplace Exposure Limits:
No known effects on the environment.
Butane-Propane Gas Mixture (A.O.):
Behaviour:
Butane-Propane Mix Gas Cartridge
1450 mg/cubic metre (600ppm) 8-hourTWA value.
No known ecological damage will be caused by this product.
Unique reference number(s):
1810 mg/cubic metre (700ppm) 15-minTWA value.
Environmental fate:
GP03
Liquefied Petroleum Gas:
When released to Air, soil and water, the majority of the product will rapidly evaporate.
Company name, address and normal telephone number:
1750 mg/cubic metre (1000ppm) 8-hourTWA value
13. Disposal Considerations
EcoGum, 349-353 High Street
2180 mg/cubic metre (1200ppm) 15-minTWA value.
Likely residues/waste product (if any):
Harborne, Birmingham, B17 9PU, England
Respiratory protection:
No known residues. Waste product: Metal Container.
T: +44 (0)161 367 1315 F: +44(0)161 367 1316
Should be used if there is a risk of high vapour concentration.
Safe handling of any residues/waste product:
Hand protection:
Any disposal route should comply with local by-laws and the requirements of the Environment
Emergency telephone no:
Use rubber gloves if in contact with liquid.
Protection Act, 1990. Liquefied Butane Gases are subject to the Control of Pollution (Special
+44(0)161 121 427 5815
Skin protection:
Waste) Regulations 1980.
2. Composition/Information on Ingredients
Wear protective overalls with long sleeves to protect exposed skin.
For disposal of surplus quantities of GoSystem gas containers, contact your local supplier, or
Preparation: BUTANE (LIQUEFIED PETROLEUM GAS)
Eye protection:
representative.
Substance CAS EC Index EEC Einics
Use goggles or face shield when handling in liquid form.
14. Transport information
number: number: number: number:
When used as a fuel source, the above controls will not be necessary.
Classification for carriage: Flammable gas
Butane 106-97-8 601-004-00-0 203-448-7 270-704-2
However, products fuelled by LPG should always be used in well ventilated areas,
ARD/RID Proper shipping name: Mixture of gases listed under 11º5º(b) Butane
Propane 74-98-6 601-003-00-5 200-827-9 200-827-9
preferably outdoors.
(Liquefied Petroleum Gas).
Hydrocarbons C3-4 Rich, Petroleum Distillates, Petroleum Gas Liquefied.
9. Physical and Chemical Properties
Preparation identification number: 1965 (1075) Mixture AO, NOS, ARD
Other extremely flammable components.
Appearance: Colourless
Land transport ADR/RID
3. Hazards Identifications
Odour: Distinctive and unpleasant (stenched)
ARD/RID Class: 2
The most important hazards are:
pH: Neutral
UN Number: 2037
EXTREMELY FLAMMABLE GAS
Boiling point/boiling point range: -42 Deg.C.
Hazard Class: SF
EXPOSURE TO HIGH CONCENTRATIONS OF VAPOUR
Flashpoint (ºC) closed cup: Less than -40 Deg.C.
Packing Group: - Combination packages
CAN LEAD TO NAUSEA, HEADACHE, DIZZINESS AND
Flammability (gas/solid): Not applicable
(Fibreboard) - Limited Quantities
IN EXTREME CASES, LOSS OF CONSCIOUSNESS,
Autoflammability: 410/550 Deg.C,
Labels: 2.1
AND IN OXYGEN DEFICIENT ENVIRONMENTS, DEATH.
Explosive properties: Not applicable
Name and description: RECEPTACLES SMALL CONTAINING
SKIN CONTACT WITH LIQUEFIED GAS CAN CAUSE COLD BURNS
Oxidising properties: Not applicable
GAS (GAS CARTRIDGE)
4. First Aid Measures
Vapour pressure: 4.1 bar @ 20 Deg.C.
Marine Transport IMDG
Immediate medical attention required: Yes
Relative density: @ 15 Deg.C:0,55 to 0,56
IMDG Class: 2
Professional assistance from physician required: Yes
Solubility (water and fat): Immiscible
UN Number: 2037
Summary of first aid is as follows:
10. Stability & Reactivity
Packing Group: - Combination packages
Inhalation: remove subject to fresh air as soon as possible using self contained breathing
Conditions to avoid:
(Fibreboard) - Limited Quantities
apparatus if appropriate to protect rescuer. If subject breathing, keep warm and at rest, preferably
Sources of ignition (store below 50 Deg.C.)
Labels: 2.1
lying down. Do not leave the subject. Remove contaminated clothing if possible. If subject has
Materials to avoid:
Name and description: RECEPTACLES SMALL CONTAINING
stopped breathing, give appropriate artificial respiration (preferably with a brook airway). When
Strong oxidising agents, e.g. chlorates which may be used in agriculture.
GAS (GAS CARTRIDGE)
breathing starts, place subject in recovery position. Do not leave the victim. Get medical assistance
Hazardous decomposition:
Air transport ICAO/IATA
as soon as possible, remove to hospital for further treatment. Give oxygen if available (short
The substances arising from the thermal decomposition of these products will largely depend
ARD/RID Class: 2.1
applications, not continuous therapy).
on the conditions bringing about the decomposition. The following substances may be expected
UN Number: 2037
Skin contact: Immediately drench skin with cold water, irrigating the affected area for 10 minutes. As
from normal combustion:
Packing Group: - Combination packages
soon as possible get medical aid and/or remove subject to hospital for specialised treatment.
Carbon Dioxide:
(Fibreboard) - Limited Quantities
Eye contact: Immediately drench eyes with cold water, irrigating the affected area for 10 minutes. As
Polycyclic Aromatic Hydrocarbons
Labels: 2.1
soon as possible get medical aid and/or remove subject to hospital for specialised treatment.
Carbon Monoxide:
Name and description: RECEPTACLES SMALL CONTAINING
Ingestion: Remove subject to fresh air as soon as possible, and follow the guidelines for 'Inhalation'
Unburned Hydrocarbons
GAS (GAS CARTRIDGE)
above.
Water:
15. Regulatory Information
5. Fire-Fighting Measures
Unidentified Organic and Inorganic Compounds
Supply label information: This information has been classified according to the requirements
Suitable extinguishing media:
Particulate Matter:
waste) Regulations 1980.
Dry powder - Use water fog/spray to contain the fire.
Nitrogen Oxides
Dangerous for supply:
Unsuitable extinguishing media:
11. Toxicological Information
Symbols: Flame
Acute Health Hazards and Advice.
Category of Danger: Extremely Flammable
Liquefied Butane Gases under normal conditions of storage and use are not likely to present a
Special exposure hazards in fire:
health hazard. The gas is heavier than air and in the event of a spillage will collect in depressions,
Risk Phrases: R12 Extremely Flammable
pits, drains, confined spaces, etc.c where it can present a health hazard
Safety Phrases: S2 Keep out of reach of children
Inhalation
Required special protective equipment for fire fighters:
Exposure to higher concentrations of Liquefied Butane Gases can lead to drowsiness,
S9 Keep container in a well ventilated place
Fires involving gases usually give off TOXIC FUMES and VAPOURS.
unconsciousness, and subsequent asphyxiation. Very high concentrations can lead to abnormal
S16 Keep away from sources of ignition
heart rhythms and possibly death.
Applicable EU Provisions and associated UK legislation:
Precautions: Inhalation of vapours should be avoided. Where, exceptionally, higher concentrations
6. Accidental Release measures
of vapour are likely to be present, e.g. in the event of a spillage in a badly ventilated area, persons
Dangerous substances Directive 67/548/EEC
Personal precautions: If there is a leakage from a small amount of gas, evacuate people from the
should not be allowed to enter the area, even in an emergency, until the atmosphere has been
The Preparations Directive 88/379/EEC
immediate danger area, and the area of the path of the gas cloud, if possible. Switch off all sources
checked and passed as safe by a competent person.
The Chemicals (Hazard Information & Packaging for supply) Regulations 2002 (SI No.1689) (CHIP3)
of ignition. No smoking. Isolate leaking container(s), if possible. Stop leak at source. If leakage
First Aid: Remove the affected person to fresh air. If breathing has stopped administer artificial
The Control of Substances Hazardous to Health (Amendment) Regulations 2004 (COSHH 2004)
cannot be stopped, remove containers(s) to an isolated area, clear of buildings, people and sources
respiration . Give external cardiac massage if necessary. Obtain medical assistance immediately.
16. Other Information
of ignition.
Skin
Training advice:
Environmental precautions: If possible, allow gas to be released slowly into the atmosphere to
Skin contact with Liquefied Butane Gases, occurring as a result of the rapid evaporation of the
The most important considerations are handling and storage. Code f Practice 7, referenced below
produce a harmless dilution. Disperse gas using a hose reel fitted with a water spray or fog nozzle, or
liquid gas, may result in cold burns.
gives all the necessary information required.
by air agitation.
Precautions: Avoid contact with the skin by the use of suitable protective clothing.
Further information:
Methods for cleaning: Attempts should be made to prevent gas vapours entering drains or gullies.
First Aid: Burns should be flushed with water to normalise temperature. Cover the burns with sterile
Code of Practice 7 Storage of Full and Empty LPG Cylinders and Cartridges.
Vapours will disperse to atmosphere if sufficient air flow is available.
dressings. Do not apply ointments or powders. Obtain medical attention.
Croner's Dangerous Substances
Where appropriate refer to information under headings "8. Exposure controls" and "13. Disposal
Eyes
Shell Gas Technical and Safety Data Sheet. Shell UK Ltd.
considerations"
Eye contact with rapidly evaporating Liquefied butane Gases may cause cold burns.
IMCO Guide
7. Handling and Storage
Precautions: If there is a risk of eye contact when handling the liquid, sensible eye protection
Approved Supply List
Handling: GoSystem gas cartridges are supplied from the factory in Fibreboard Combination
should be used.
Other.
Packages of 12 gas cartridges per package.
First Aid: Burns should be flushed with water to normalise temperature. Cover the eye with a sterile
ARD/RID Regulations
Packages should be handled with care and kept upright when transferring the packages.
dressing and obtain medical attention immediately.
The data contained in this Safety Sheet has been supplied as a requirement by the Chemicals
Storage: the storage of LPG is subject to legislative controls. The primary piece of legislation
Ingestion
(Hazard Identification and Packaging for Supply) Regulations 2002, for the purpose of protecting
affecting the storage of LPG is the Highly Flammable liquids and Liquefied Petroleum Gases
Whilst this is not a normal hazard associated with Liquefied Butane Gases, abuse by inverting gas
the health and safety of industrial and commercial users who are deemed capable of
Regulations 1972. LPG must be stored in purpose built Containment systems.
containers can result in the liquid being ingested. In these circumstances the hazards are the same
understanding and acting on the information provided.
LPGA Code of practice 7 should be consulted in order to comply with the legislation (obtainable
as for inhalation.
Please ensure that it is passed to the appropriate person(s) in your company, who are capable of
from HMSO book shops and the L.P. Gas Association).
Precautions: Liquefied gas should never be ingested.
acting on the information.
ECOGUM GP03
Approach fire or gas leaks with caution from upwind and with respiratory protection if available.
1. Identification of the Substance/Preparation and Company Substance or
preparation trade name:
Standard water jet fire hoses can spread the fire and may cause dangerous explosions.
Danger of explosion in enclosed space - keep nearby gas containers cool with water spray.
GB