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User Manual 

20 

Keep powder or windows stored in a cool, dry container, with appropriate 
safety labelling.

 

Data Sheet For Germanium 

 

General 

 

Hard and very brittle material, but can be shaped, cut and polished to form 
spectral transmission window or crystal for ATR spectroscopy. 
Because of its high Refractive Index value suffers from large reflection losses 
but these can be improved with antireflection optical coatings  
Is temperature sensitive and loses transmission when heated. (Is optically 
opaque to IR transmission at 190°C temperature.) 
Insoluble in water and alcohols. Soluble in hot sulphuric acid and aqua regia. 
Element symbol: Ge 
Chemical Abstracts Service (CAS) No: 7440-56-4. 

 

Physical Data 

 

Appearance: Greyish/black, opaque, elemental, metallic solid. Has no odour. 
Melting point: 737°C. 

 

Boiling point: 2830°C. 
Vapour pressure: 2.66 x 10

-56

 mm Hg at 25°C. 

Specific gravity: 5.323 g cm

-3

Solubility in water: Insoluble 
Hardness: 780 Kg/mm

2

Refractive Index: 4.01 (at 2000cm-1 - wavenumbers). 
Spectroscopic transmission range: 5,500 to 500 cm-1 (wavenumbers). 

 

Stability 

 

Stable. 

 

Toxicology 

 

Harmful if ingested in large amounts, if inhaled, or if in repeated 
contact with the skin.  
 

 

Personal Protection 

Always wear safety spectacles and gloves when handling the window or 
crystal material.  

Allow for adequate ventilation. 

 

Storage 

Summary of Contents for Gateway ATR

Page 1: ...Gateway ATR Flow Through Top Plate User Manual 2I 11116 5...

Page 2: ......

Page 3: ...Gateway ATR Flow Through Top Plate User Manual 2I 11116 5...

Page 4: ...THE CRYSTAL IN THE TOP PLATE ASSEMBLY 15 CLEANING THE GATEWAY ATR FLOW THROUGH TOP PLATE ASSEMBLY INTACT 17 NOTES ON CLEANING 17 DATA SHEET FOR ZINC SELENIDE 19 DATA SHEET FOR GERMANIUM 20 DATA SHEET...

Page 5: ...and a clamp assembly GS11171 See user instruction manual 2I 11165 4 Note Any Gateway ATR Top Plate assembly can also be used on older Benchmark ATR optical units P N s GS11160 GS11110 and GS11180 Usin...

Page 6: ...nt ATR crystal material in the Top Plate if desired Any of the crystal materials usable with the Gateway ATR system ZnSe germanium or silicon can be placed into the Gateway ATR Flow Through Top Plate...

Page 7: ...on Si are the three crystal materials of choice that can be used Caution Out of these three different crystal types ZnSe is the most potentially hazardous material with respect to toxicity risk in use...

Page 8: ...crystal or as specified from germanium and silicon options ATR spectrum of the crystal as fitted to the Top Plate assembly to show its background throughput Clear silicone tubing for sample flow conne...

Page 9: ...from the alignment procedure using either of these two Top Plates When subsequently placing the Flow Through Top Plate onto the optical unit as a replacement for either the Trough GS11166 or Flat GS1...

Page 10: ...the round hole 1 is placed over the right side location pin 3R and the slot hole 2 is placed over the left side location pin 3L as viewed from the front of the optical unit The main body plate 4 of t...

Page 11: ...Gateway ATR Flow Through Top Plate 9 Fig 3 Fitting of Gateway ATR Flow Through Top Plate to the Gateway Optical Unit 1 2 4 3L 3R R...

Page 12: ...secured to the sample flow inlet and outlet ports 5 of the Top Plate assembly Important The tubing connected to the ports 5 on the Top Plate should be tested initially for liquid flow away from insta...

Page 13: ...is is being used to circulate the sample flow The liquid sample passes through the Flow Through Top Plate across the top surface of the ATR crystal 7 contained within for 6 ATR reflection measurement...

Page 14: ...ng procedure should be adopted Note It is normally easier to work on the Top Plate assembly having disconnected the silicone flow tubing from the inlet and outlet sample flow ports 5 Important For saf...

Page 15: ...7 itself has been removed from its centralised position in its recess of the main body plate 4 Therefore support the crystal 7 and the lead pad 11 with one hand and turn over the Top Plate assembly so...

Page 16: ...vent and apply a gentle sonication cleaning of the items The action of the sonic agitation of the solvent may help to loosen the lead pad 11 away from the crystal such that when the items are removed...

Page 17: ...side channel recess of the main body plate 4 See as for Fig 8 Important Ensure that the sample port introduction holes 5 through the top section plate 6 are not blocked or covered by an incorrect posi...

Page 18: ...pes but particularly ZnSe are brittle crystal materials and uneven pressure or over tightening may fracture the crystal 7 6 Stand the re assembled Flow Through Top Plate on a tissue covering a work su...

Page 19: ...al 7 is suitably clean by taking a spectral measurement before storage of the Top Plate assembly in a clean dry cabinet for example the Specacabinet P N GS19100 at about 40 50 C Notes On Cleaning When...

Page 20: ...as resilient as germanium or silicon crystals Scratches and blemishes to the ATR crystal 7 surface will result in poor light throughput for the ATR technique and an overall degradation in the Accesso...

Page 21: ...granular powder or amber coloured window material Melting point 1515 C at 1 8 atmospheres 26 5psi Solubility in water 0g 100g at 0 C Hardness 120 Kg mm2 Refractive Index 2 43 at 2000cm 1 wavenumbers S...

Page 22: ...n water and alcohols Soluble in hot sulphuric acid and aqua regia Element symbol Ge Chemical Abstracts Service CAS No 7440 56 4 Physical Data Appearance Greyish black opaque elemental metallic solid H...

Page 23: ...S No 7440 21 3 Physical Data Appearance Grey lustrous solid or grey powder Melting point 1410 C Boiling point 2355 C Solubility in water 0g 100g at 0 C Hardness 1150 Kg mm2 Refractive Index 3 42 at 20...

Page 24: ...ough Top Plate 5 Sample flow connection port 6 Top section plate of the Flow Through Top Plate 7 ATR crystal 8 Isolast gasket seal 9 M3 x 16mm cap head screw for lower clamp plate 10 10 Lower clamp pl...

Page 25: ...Gateway ATR Flow Through Top Plate 23 P N GS11150 Gateway ATR Isolast gaskets for 550ul Flow Through Top Plate assemblies pkt 3...

Page 26: ...For Sample of Refractive index 1 5 1000cm 1 0 9 m For Sample of Refractive index 1 5 1000cm 1 Typical Light Throughput When Aligned 20 to 30 Transmission 20 to 30 Transmission 20 to 30 Transmission A...

Page 27: ...ffixed to the underside of the Top Plate assembly To help you please use the grid below to fill in the serial number information of the Gateway ATR Flow Through Top Plate assembly you have received If...

Page 28: ...te www systems eng co jp Spain Teknokroma S Coop C Ltda Barcelona Tel 93 674 8800 Fax 93 675 2405 email comercial teknokroma es Switzerland Portmann InstrumentsAG Biel Benken Tel 061 726 6555 Fax 061...

Page 29: ...PECAC INC 414 Commerce Drive Suite 175 Fort Washington PA 19034 USA Tel 215 793 4044 Fax 215 793 4011 SPECAC LTD Unit 12 Science Innovation Centre Halo Business Park Orpington Kent BR5 3FQ Tel 44 0 16...

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