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August 2000

NICKEL METAL HYDRIDE HANDBOOK, PAGE 

7

Overview

As electronic products have come to feature more
sophisticated functions, more compact sizes and
lighter weights, the sources of power that operate
these products have been required to deliver in-
creasingly higher levels of energy. To meet this
requirement, nickel-metal hydride batteries have
been developed and manufactured with nickel hydro-
xide for the positive electrode and hydrogen-absorb-
ing alloys, capable of absorbing and releasing hydro-
gen at high-density levels, for the negative electrode.
Because Ni-MH batteries have about twice the
energy density of Ni-Cd batteries and a similar
operating voltage as that of Ni-Cd batteries, they are
expected to become a mainstay in the next genera-
tion of rechargeable batteries.

NICKEL METAL HYDRIDE BATTERIES

Construction

Nickel-metal hydride batteries consist of a positive
plate containing nickel hydroxide as its principal active
material, a negative plate mainly composed of hydro-
gen-absorbing alloys, a separator made of fine fibers,
an alkaline electrolyte, a metal case and a sealing
plate provided with a self-resealing safety vent.  Their
basic structure is identical to that of Ni-Cd batteries.
With cylindrical nickel-metal hydride batteries, the
positive and negative plates are seperated by the
separator, wound into a coil, inserted into the case,
and sealed by the sealing plate through an electrically
insulated gasket.
With prismatic nickel-metal hydride batteries, the
positive and negative plates are sandwiched together
in layers with separators between them, inserted into
the case, and sealed by the sealing plate.

Summary of Contents for HHR160A

Page 1: ...to become a mainstay in the next genera tion of rechargeable batteries NICKEL METAL HYDRIDE BATTERIES Construction Nickel metal hydride batteries consist of a positive plate containing nickel hydroxide as its principal active material a negative plate mainly composed of hydro gen absorbing alloys a separator made of fine fibers an alkaline electrolyte a metal case and a sealing plate provided with...

Page 2: ...is now employing its own MmNi5 alloy which uses Mm misch metal an alloy consist ing of a mixture of rare earth elements for metal A Principle of Electrochemical Reaction Involved in Batteries Positive electrode Negative electrode Overall reaction Charge Discharge Ni OH 2 M hydrogen absorbing alloy absorbed hydrogen M M Charge Discharge Charge Discharge e OH NiOOH H O MH ab H O NiOOH ab ab 2 2 2 OH...

Page 3: ...eries nickel metal hydride batteries can be repeatedly charged and discharged for about 500 cycles example IEC charge and discharge conditions Rapid charge in approx 1 hour Nickel metal hydride batteries can be rapidly charged in about an hour using a specially designed charger Excellent discharge characteristics Since the internal resistance of nickel metal hydride batteries is low continuous hig...

Page 4: ...characteristics The discharge characteristics of nickel metal hydride batteries are affected by current temperature etc and the discharge voltage characteristics are flat at 1 2V which is almost the same as for Ni Cd batteries The discharge voltage and discharge efficiency decrease in proportion as the current rises or the temperature drops As with Ni Cd batteries repeated charge and discharge of ...

Page 5: ...tions of use Under proper conditions of use example IEC charge and discharge conditions these batteries can be charged and discharged for more than 500 cycles Cycle life characteristics Safety When the internal pressure of these batteries rises due to overcharge short circuiting reverse charge or other abuse or misuse the self resealing safety vent is activated to prevent battery damage Panasonic ...

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