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Suva

®

 HP81 offers the highest efficiency versus

R-502, with slightly better capacity. However, the
higher HCFC-22 content results in compressor
discharge temperatures in the range of 14°C (25°F)
higher than that of R-502, which makes Suva

®

HP81 most suited for medium-temperature systems
such as ice machines.

Suva

®

 404A (HP62) offers the best overall proper-

ties when compared with R-502. Capacity and effi-
ciency values should be equivalent to R-502, and
compressor discharge temperatures may be up to
9°C (14°F) lower than R-502, which may equate to
longer compressor life and better lubricant stability.

In addition, the heat transfer characteristics of
all the Suva

®

 HP products appear to be better than

R-502, so any loss of compression efficiency may
be offset by improvements in heat transfer.

Due to the differences in operating characteristics
described above, Suva

®

 HP80 and HP81are typi-

cally selected for different applications. Suva

®

HP81 is preferred where higher energy efficiency
and capacity are needed and where the higher dis-
charge temperatures will not create operating diffi-
culties. Both Suva

®

 HP80 and Suva

®

 404A (HP62)

are full-range R-502 replacements, with Suva

®

HP80 preferred for retrofitting of existing systems,
and Suva

®

 404A (HP62) preferred for new equip-

ment. Suva

®

 404A (HP62) can also be used for

retrofitting existing equipment where HFCs are
desired. 

Table 2

 shows markets that currently use

each of these refrigerants.

Table 2

DuPont™ Suva

®

 HP Refrigerant

Market Applications

Product

Medium Temperature

Low Temperature

Suva

®

 HP81

Ice Machines

To Be Determined

Food Service
Vending
Supermarket

Suva

®

 HP80

Supermarket

Supermarket

Transport

Transport
Food Service

Suva

®

 404A

(HP62)

All

Physical Properties

General physical properties of the Suva

®

 HP refrig-

erants are shown in 

Table 3

. Pressure-enthalpy dia-

grams for the Suva

®

 HP refrigerants are shown in

Figures 1–6

.

Additional physical property data may be found
in other DuPont publications. Bulletin ART-18
contains viscosity, thermal conductivity, and heat
capacity data for saturated liquid and both saturated
and superheated vapor. ART-18 also contains heat
capacity ratios for saturated and superheated vapor.

Thermodynamic tables in English and SI units are
available in Bulletins T-HP80-ENG, T-HP80-SI,
T-HP81-ENG,  T-HP81-SI, T-HP62-ENG, and
T-HP62-SI for Suva

®

 HP80, Suva

®

 HP81, and

Suva

®

 404A (HP62).

Chemical/Thermal Stability

Stability with Metals

Stability tests for refrigerant with metals are typi-
cally performed in the presence of refrigeration
lubricants. Results of sealed tube stability tests
available for R-502/mineral oil and alkylbenzene
lubricants have shown long-term stability in contact
with copper, steel, and aluminum in actual refrig-
eration systems. Mineral oils, alkylbenzene, mix-
tures of mineral oil/alkylbenzene and polyol esters
(POE) are all possible candidates for use with
Suva

®

 HP80 and HP81; POE are proposed lubri-

cants for use with Suva

®

 404A (HP62).

The method followed was generally the same as
ASHRAE 97 with several minor modifications. A
3-mL volume of refrigerant/lubricant solution was
heated in the presence of copper, steel, and alumi-
num coupons in an oven for 14 days at 175°C
(347°F). Both the neat lubricant and a mixture of
lubricant and refrigerant (50/50 volume ratio) were
tested. Visual ratings were obtained on both the
liquid solutions and the metal coupons after the
designated exposure time. The visual ratings range
from 0 to 5, with 0 being best.

After the visual ratings were obtained, sample tubes
were opened and the lubricant and refrigerant (if
present) were analyzed. The lubricant was typically
checked for halide content and viscosity, while the
refrigerant was examined for the presence of de-
composition products. 

Table 4

 summarizes typical

data for Suva

®

 HP refrigerants. Visual ratings are

listed for the neat lubricant, the lubricant/refriger-
ant solution, and the three metals that were present
in the lubricant/refrigerant solutions. Viscosity was
determined on the unused lubricant, the tested neat
lubricant, and the lubricant tested in the presence
of refrigerant. Decomposition products were deter-
mined in some cases. Typical measurements for
decomposition products is in the low parts per
million (ppm) range.

Suva

®

 HP81 tests with various lubricants indicate it

has adequate chemical stability with these lubri-
cants. In addition, we believe that HP80 will have
similar behavior due to the same refrigerants being
used in the formulation. Suva

®

 404A (HP62) tests

with common POE lubricants indicate that chemi-
cal stability of Suva

®

 404A (HP62) with common

metals used in refrigeration systems is acceptable.

2

Summary of Contents for Suva 404A

Page 1: ...nformation P HP DuPont Suva HP80 R 402A refrigerant DuPont Suva HP81 R 402B refrigerant DuPont Suva 404A HP62 refrigerant DuPont Suva HP Refrigerants Properties Uses Storage and Handling DuPont Suva r...

Page 2: ...Toxicity 13 Cardiac Sensitization 15 Skin and Eye Contact 15 Spills or Leaks 15 Combustibility of Suva HP Refrigerants 15 Air Monitors and Leak Detection 16 Types of Detectors 16 Nonselective Detector...

Page 3: ...CF2 HCl 75 45 6 86 47 HFC 125 Pentafluoroethane CF3 CHF2 354 33 6 120 02 HFC 134a 1 1 1 2 Tetrafluoroethane CF3 CH2 F 811 97 2 102 0 HFC 143a 1 1 1 Trifluoroethane CF3 CH3 420 46 2 84 08 HC 290 Propan...

Page 4: ...d SI units are available in Bulletins T HP80 ENG T HP80 SI T HP81 ENG T HP81 SI T HP62 ENG and T HP62 SI for Suva HP80 Suva HP81 and Suva 404A HP62 Chemical Thermal Stability Stability with Metals Sta...

Page 5: ...essure at 25 C 77 F kPa 1337 1254 1255 psia 194 0 181 9 182 0 Heat of Vaporization kJ kg 194 0 210 0 202 1 at Boiling Point Btu lb 83 5 90 3 87 0 Thermal Conductivity at 25 C 77 F Liquid W m K 6 91E 2...

Page 6: ...Figure 1 DuPont Suva 404A HP62 Pressure Enthalpy Diagram SI Units 4 DuPont Suva 404A HP62 Pressure Enthalpy Diagram SI Units...

Page 7: ...Figure 2 DuPont Suva 404A HP62 Pressure Enthalpy Diagram English Units 5 DuPont Suva 404A HP62 Pressure Enthalpy Diagram English Units...

Page 8: ...Figure 3 DuPont Suva HP80 R 402A Pressure Enthalpy Diagram SI Units 6 DuPont Suva HP80 R 402A Pressure Enthalpy Diagram SI Units...

Page 9: ...Figure 4 DuPont Suva HP80 R 402A Pressure Enthalpy Diagram English Units 7 DuPont Suva HP80 R 402A Pressure Enthalpy Diagram English Units...

Page 10: ...Figure 5 DuPont Suva HP81 R 402B Pressure Enthalpy Diagram SI Units 8 DuPont Suva HP81 R 402B Pressure Enthalpy Diagram SI Units...

Page 11: ...Figure 6 DuPont Suva HP81 R 402B Pressure Enthalpy Diagram English Units 9 DuPont Suva HP81 R 402B Pressure Enthalpy Diagram English Units...

Page 12: ...xist ing equipment or preparing storage and handling facilities Because the Suva HP products have been designed as refrigerants the compatibility data summarized here will include materials commonly u...

Page 13: ...ND 7 Cl ppm ND ND 7 values for Suva HP80 assumed to be comparable Suva 404A HP62 with various lubricants Suva 404A HP62 Suva 404A HP62 Suva 404A HP62 Suva 404A HP62 with Mineral Oil with Alkylbenzene...

Page 14: ...not occur when PET is aged in HP81 or Suva 404A HP62 with ester lubricants at 150 C 302 F Polyesterimide Enameled Motor Wire amide imide overcoated NEMA NW 35C No extracts or precipitates were observ...

Page 15: ...rtant to know that the lubricants used with the Suva HP refrigerants will return to the compressor using existing equipment designs Different compressor and equipment manufacturers will recommend lubr...

Page 16: ...ses 1 phase w polyol ester 60 80 1 phase Suva HP80 w mineral oil 50 65 72 2 phases 2 phases inversion w alkylbenzene 50 66 72 2 phases 2 phases inversion w polyol ester 50 72 1 phase Suva 404A HP62 w...

Page 17: ...ys wear protective clothing when there is a risk of exposure to liquid refrigerants Where splashing of refrigerant may occur always wear eye protection and a face shield Spills or Leaks If a large rel...

Page 18: ...d should never be filled while under positive air pressure Filled cylinders should periodically be analyzed for air nonabsorbable gas or NAG Refrigerant Recovery Systems Efficient recovery of refriger...

Page 19: ...erence from other compounds With Suva HP refrigerants using compound specific detectors may be difficult because the different mixtures often contain similar types of compounds In an area where differ...

Page 20: ...erants from the United States The general construction of a one ton returnable container is shown in Figure 7 Note that one end of the container is fitted with two valves When the container is turned...

Page 21: ...ating step 2 until R 502 and moisture levels are within acceptable limits 5 Refilling the system with Suva HP refrigerant This is a simplified outline of what is actually a lengthy procedure Your DuPo...

Page 22: ...pment are the same as those on the container valve outlets Keep valves tightly closed and valve caps and hoods in place when the containers are not in use Store containers under a roof to protect them...

Page 23: ...dure with no analytical testing of refrigerant Suva HP refrigerants may be recycled using many of the devices now available In the United States the EPA sets standards for these devices Recycle is alr...

Page 24: ...111 DuPont Far East Inc 6th Floor Bangunan Samudra No 1 JLN Kontraktor U1 14 SEK U1 Hicom Glenmarie Industrial Park 40150 Shah Alam Selangor Malaysia Phone 60 3 517 2534 DuPont Korea Inc 4 5th Floor A...

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