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6.5

Short-circuit values

The typical short-circuit value in
amperes for a block battery cell is
approximately 9 times the ampere-
hour capacity for an L type block, 
16 times the ampere-hour capacity 
for an M type block and 28 times 
the ampere-hour capacity for an 
H type block.

The block battery with conventional
bolted assembly connections will
withstand a short circuit current of this
magnitude for many minutes without
damage.

6.6

Open circuit loss

The state of charge of the block cell
on open circuit slowly decreases 
with time due to self-discharge. In
practice this decrease is relatively
rapid during the first two weeks, but
then stabilizes to about 2 % per month
at 20°C.
The self-discharge characteristics of 
a nickel-cadmium cell are affected by
the temperature. At low temperatures,
the charge retention is better than at
normal temperature, and so the open
circuit loss is reduced. However, the
self-discharge is significantly
increased at higher temperatures.

The typical open circuit loss for 
the block battery for a range 
of temperatures which may be
experienced in a stationary
application is shown in Figure 2.

6.7

Cycling

The block battery is designed to
withstand the wide range of cycling
behavior encountered in stationary
applications. This can vary from low
depth of discharges to discharges of
up to 100 % and the number of cycles
that the product will be able to
provide will depend on the depth 
of discharge required.

The less deeply a battery is cycled,
the greater the number of cycles it is
capable of performing before it is
unable to achieve the minimum
design limit. A shallow cycle will give
many thousands of operations,
whereas a deep cycle will give only
hundreds of operations.

Figure 3 gives typical values for the
effect of depth of discharge on the
available cycle life, and it is clear
that when sizing the battery for a
cycling application, the number and
depth of cycles have an important
consequence on the predicted life 
of the system.

6.8

Effect of temperature 

on lifetime

The block battery is designed as 
a twenty year life product, but as 
with every battery system, increasing
temperature reduces the expected life.
However, the reduction in lifetime
with increasing temperature is very
much lower for the nickel-cadmium
battery than the lead-acid battery.

The reduction in lifetime for the nickel-
cadmium battery, and for comparison,
a high quality lead acid battery is
shown graphically in Figure 4. The
values for the lead acid battery are
as supplied by the industry and found
in Eurobat and IEEE documentation.

14

BlockBat  3/11/98  10:12  Page 17

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Contents

Содержание SBL

Страница 1: ...Nickel cadmium block battery Technical manual...

Страница 2: ...lly safe 4 2 13 Low life cycle cost 4 3 Electrochemistry of nickel cadmium batteries 5 4 Construction features of the block battery 6 4 1 Plate assembly 7 4 2 Separation 8 4 3 Electrolyte 8 4 4 Termin...

Страница 3: ...technical manuals are available which address the particular characteristics of these ranges 6 7 Cycling 14 6 8 Effect of temperature on lifetime 14 6 9 Water consumption and gas evolution 16 7 Batter...

Страница 4: ...nd operating characteristics of the Saft Nife pocket plate block battery to enable a successful battery system to be achieved A battery which while retaining all the advantages arising from nearly 100...

Страница 5: ...see section 9 2 Mechanical abuse 2 8 High resistance to electrical abuse The block battery will survive abuse which would destroy a lead acid battery for example overcharging deep discharging and high...

Страница 6: ...in the electrochemistry of the process and are naturally corroded during the life of the battery The charge discharge reaction is as follows During discharge the trivalent nickel hydroxide is reduced...

Страница 7: ...blocks of 1 10 cells depending on the cell size Plate group bus Connects the plate tabs with the terminal post Plate tabs and terminal post are projection welded to the plate group bus Separating grid...

Страница 8: ...ssembly The nickel cadmium cell consists of two groups of plates the positive containing nickel hydroxide and the negative containing cadmium hydroxide The active materials of the Saft Nife pocket pla...

Страница 9: ...n the cell plates irrespective of the charge level In most applications the electrolyte will retain its effectiveness for the life of the battery and will never need replacing However under certain co...

Страница 10: ...d 4 They can be recognized from the block dimensions as follows Block width mm Block height mm Plate module 123 194 1 123 264 2 195 349 3 195 405 4 Table 1 Correlation between block dimensions and pla...

Страница 11: ...e different discharge types The choice is related to the discharge time and the end of discharge voltage There are of course many applications where there are multiple discharges and so the optimum ra...

Страница 12: ...cations 5 3 Type H The SBH is designed for applications where there is a demand for a relatively high current over short periods usually less than 30 minutes in duration The applications can have freq...

Страница 13: ...sistance of a block battery cell depends on the performance type and at normal temperature has the values given in Table 3 in milliohms per Ah of capacity To obtain the internal resistance of a cell i...

Страница 14: ...e for operating temperatures from 30 C to 50 C Figure 1 a Temperature derating factors for H type plate 1 2 1 0 8 0 6 0 4 0 2 40 20 0 20 40 Derating factor special electrolyte required for continuous...

Страница 15: ...ncountered in stationary applications This can vary from low depth of discharges to discharges of up to 100 and the number of cycles that the product will be able to provide will depend on the depth o...

Страница 16: ...s reduced to less than 1 year if used at 50 C 15 Figure 2 Capacity loss on open circuit stand 100 90 80 70 60 50 0 50 100 150 200 250 300 350 400 Percentage of initial capacity 40 C Open circuit perio...

Страница 17: ...f discharge of the electrodes The overcharge current is a function of both voltage and temperature so both have an influence on the consumption of water Figure 5 gives typical water consumption values...

Страница 18: ...previous discharge The factors used for this will depend on the depth of discharge the rate of discharge and the charge voltage and current A requirement for a high state of charge does not justify a...

Страница 19: ...and so the minimum voltage for the single level and the two level charge voltage is the normally recommended value This also helps within a voltage window to obtain the lowest and most effective end o...

Страница 20: ...w than the two rate charger The two rate charger has an initial high voltage stage to charge the battery followed by a lower voltage maintenance charge This allows the battery to be charged quickly an...

Страница 21: ...tage 1 50 volts per cell Charge Time hours Charging Voltage 1 40 volts per cell Charging Voltage 1 45 volts per cell Charging Voltage 1 55 volts per cell Current Limit 0 2 C5A Temperature 20 25 C H ty...

Страница 22: ...harge times from a fully discharged state for the L block 130 120 110 100 90 80 70 60 50 40 30 20 10 0 0 5 10 15 20 25 30 35 Available Capacity of rated capacity Charging Voltage 1 50 volts per cell C...

Страница 23: ...A constant current first charge is preferable and this should be such as to supply 300 of the rated capacity of the cell Thus a 250 Ah cell will require 750 ampere hours input e g 50 amperes for 15 h...

Страница 24: ...cid batteries this will lead to failure of the battery and is unacceptable The block battery is designed to make recovery from this situation possible Overcharge In the case of the block battery with...

Страница 25: ...0 45 liters of hydrogen 10 Installation and storage 10 1 Batteries on arrival On receiving the battery open the cases and check for any indication of damage in transit Remove the cells and any access...

Страница 26: ...0 45 liters of hydrogen 10 Installation and storage 10 1 Batteries on arrival On receiving the battery open the cases and check for any indication of damage in transit Remove the cells and any access...

Страница 27: ...of 2 for example the air in the room will need changing 3 2 1 5 times per hour In practice a typical figure for natural room ventilation is about 2 5 air changes per hour and so in this case it would...

Страница 28: ...of 2 for example the air in the room will need changing 3 2 1 5 times per hour In practice a typical figure for natural room ventilation is about 2 5 air changes per hour and so in this case it would...

Страница 29: ...tery operations the electrolyte will retain its effectiveness for the life of the battery Thus normally it is not necessary to change the electrolyte However under certain battery operating conditions...

Страница 30: ...Saft Argentina SA Buenos Aires Tel 54 11 4 686 1994 Fax 54 11 4 686 1925 AUSTRALIA Saft Pty Ltd Seven Hills Tel 61 2 9674 0700 Fax 61 2 9620 9990 BELGIUM NV Safta SA Brussels Tel 32 2 556 44 00 Fax 3...

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