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Important: Please Read and Follow Instructions Carefully Before Initial Use

  Place plenty of tap water and leave it for a while.

※Dry electrodes will result in abnormal measurement values.

Calibration points  -1- 
Calibration can be done at 3 points (pH 4.01, pH 6.86, and pH 9.18).
If the sample is above pH 6.9, calibration can be done at 2 points (pH 6.86 and pH 9.18). 
If the sample is less than pH 6.9, calibration can be done at 2 points (pH 4.01 and pH 6.86).
Press the CAL button to perform calibration for either pH 4.01, pH 6.86, or pH 9.18. 
*If the power is not turned on, press the START button to turn on the power, then perform the following procedure.
Calibration points  -2- 
Calibration can be done at 3 points (pH 4.01, pH 7.00, and pH 10.01).
If the sample is above pH 7.0, calibration can be done at 2 points (pH 7.00 and pH 10.01). 
If the sample is less than pH 7.0, calibration can be done at 2 points (pH 4.01 and pH 7.00).
Press the CAL button to perform calibration for either pH 4.01, pH 7.00, or pH 10.01. 
*If the power is not turned on, press the START button to turn on the power, then perform the following procedure.

*Turning  excessively  may

cause malfunction.

       Open

Close

OP

EN

CLO

SE

O

P

E

N

C

L

O

S

E

【Caution】
◇ Do not scratch the electrode.
◇ The instrument is water-resistant, not waterproof, and
should not be submerged.

CAL

Place plenty of tap water 

and leave it for a while.

◇The insufficient amount of sample will result

in abnormal measurement or calibration.

O

P

EN

CL

O

SE

OP

EN

CLO

SE

Press to set date, time,
and delete data history.

START button & CAL button

 tap water

At least 0.6mL.

1.Wipe off the sample.

2.Apply tap water.

Wipe off the tap water. 

(Remove the sample

(Repeat several times.)

with a plastic pipette.)  

1.Wipe off the sample.

2.Rinse with tap water.

3.Wipe off the tap water. 

(Remove the sample 
 with a plastic pipette.) 

Or

PAL-pH

Cat.No. 4311

【Caution】
◇Perform calibration before initial use and at least once a month to maintain precision and accuracy.
◇Measure a standard calibration solution. When the measurement value falls outside of the expected range, perform

calibration.

◇When the time lapsed since last measurement is more than 2 weeks, it is recommended to calibrate the instrument.
◇If the ambient temperature changes during the daily work with this instrument, it needs the calibration again.

【Caution】
◇Do not splash water above 50℃. The plastic may warp, which may compromise the water resistance.

・When measuring hot samples, place only the necessary amount and do not let it overflow from the sample stage well.
・When hot water is necessary to clean off hardened samples, use water-soaked gauze around the sample stage and keep

hot water away from the body case.

◇In rare cases, a measurement value may be displayed even if there is not sample placed on the electrode section. In such 

instances, simply place some sample on the electrode section and press the START button. Measurements will be taken normally.

When measuring samples such as strong acids and high alkaline, take a quick measurement and rinse off any remaining
sample with tap water.

<LCD Auto Shut-off>
The instrument will turn itself off after 5 minutes of inactivity. To manually turn it off, hold down the START button for more 
than 2 seconds.

The following messages alert the user when an operation has failed.

  L o

The battery is low.
Display will turn off after 10 seconds.

L L L

The sample measured is outside the 
measurement range.
The START button was pressed with nothing  
on the electrode section.

H H H

The sample measured is outside the 
measurement range.
The START button was pressed with nothing  
on the electrode section.

A A A

The CAL button was pressed with nothing  
on the electrode section.

E E E

The START button was pressed with nothing  
on the electrode section.

The detection temperature was over 45℃. A 
pH value was displayed (accuracy is not 
guaranteed).

The detection temperature was less than 
5℃. A pH value was displayed (accuracy is 
not guaranteed).

H H H

LLL

Digital Hand-held "Pocket" pH Meter

R

ATAGO instruments are rigorously inspected to ensure each unit meets the highest standards of quality assurance.

Safety Instructions

Read and follow all safety instructions before operating the instrument. Failure to comply with the following instructions may 
result in personal injury or property damage.

WARNING

◇Ensure safety when handling hazardous materials. Observe precautionary measures and use protective equipment, Be

aware of the hazards of such chemicals and emergency response guidelines.

◇ATAGO may not be held liable for any injury or damage arising in connection with handling of hazardous materials during

the use of the instrument.

◇Do not drop the instrument or subject it to strong physical shock.
◇Do not attempt to repair, modify, or disassemble the instrument.

Thank you for purchasing the instrument. Carefully read and follow all instructions. Keep this manual for future reference.
A small amount of solution may leak from the reference electrode. This is normal and does not affect the unit's performance.

〈International Protection Classification IP65〉
◇The instrument is water-resistant, not waterproof, and should not be submerged.

〈Chemical Resistance of Body Case〉
◇The body case is made of PC. Do not expose it to water vapor or solvents. See the list of “Solvents Harmful to Body

Case.”

◇Do not use metal tools, such as a spoon, as they may scratch

the glass electrode, resulting in erroneous measurements.

◇Do not measure organic solvents, oils, adhesives, cement,

alcohol, surfactants,, polymer solvents or hydrogen flouride.

◇Do not use water above 50℃ to rinse the instrument.
◇Only use the specified battery type. Observe proper polarities,

properly aligning the anodes and cathodes.

◇Store the instrument away from direct sunlight/heat sources

and excessive amounts of dust/debris.

◇Do not expose the instrument to a rapid change in ambient

temperature.

◇Do not subject the instrument to strong vibration.
◇Do not subject the instrument to extreme cold temperature.
◇Do not place the instrument under anything heavy.
◇Loosen the battery compartment cover for air transportation.

CAUTION

◇Carefully read this manual to have basic knowledge of

the function of each component.

◇ATAGO is not liable for any loss and damage caused by

the measurement and use of this instrument.

◇ATAGO shall not be held responsible for any or all

damages that may result from using the instrument for
those other than its intended purpose (measurement of
pH level of a liquid sample).

◇If the standard solution for calibration comes in contact

with hands or skin, immediately rinse with plenty of
water.

The glass electrode is fragile; be careful not to damage
it. Glass shards may cause injury.

【Caution】
◇ Please remove the tape in the battery compartment before first use.
◇ Fasten the battery compartment cover tightly to prevent water ingress or poor connection,

which will cause erroneous measurements. Push the cover in firmly and turn.

◇ When the O-ring on the cover is dirty or damaged, the water resistance may be compromised.
◇ When the battery icon indicates the low power level (      ), replace both batteries with a 

brand new set of AAA alkaline batteries (1.5V).

◇ Static images may occasionally appear on LCD. Such retained pixel charges do not indicate a

faulty display, consume the battery power, or affect the instrument’s performance in any way.

◇ Check the expiration dates on batteries before purchase.
◇Calibrate the instrument after the batteries are replaced.

O-ring

1.

Insert a coin in the

groove on the battery
compartment cover. Turn
the coin counterclockwise
to remove the cover.

2.

Insert batteries,

observing the correct
polarity.

3.

Align the cover and push

it down.

4.

Close the battery

compartment cover by
pushing the cover in with a
coin in the groove and
turning it clockwise until it
stops.

Groove

Measurement results and remaining 
battery charge are displayed.

Press to perform calibration.

Reference electrode

Glass electrode

Sample stage

CAL button

Lanyard hole

LCD

START button (Power button)

Place and remove batteries from here.

Battery compartment

Apply samples on the electrode in 
the center of the sample stage.

Press to take measurements and hold 
down to turn off the display.

Instruction Manual

Parts

Contents

Introduction

Measurement

Calibration

Replacing the Batteries

Cleaning

Error Messages

Main unit…1   Instruction Manual (this book)…1    Calibration Report …1      AAA batteries…2      
Standard solution for calibration……… pH4.01…1  pH6.86…1 pH9.18…1        PAL Silicone Cover…1

For samples containing oils or fats:

Clean oily residues on the electrode section with 
ethyl alcohol. Then rinse the electrode section with 
tap water throughly.

Ethyl

alcohol

3.

After the

display flashes

"---",the

measurement

value is displayed.

2.

Press the

START button.

*If the power is not turned on, press the START button to turn on the power, then perform the following procedure.

Repeat until measurement 

values are stabilized.

1.

Place enough sample to

cover the entire electrode

section.

At least 0.6mL of sample

<When measuring with higher precision>

b.

Place the sample so 

as to cover the entire 

electrode section again.

a.

Wipe away the 

sample.

At least 0.6mL of sample

Perform the following procedure (a) and 
(b) before step 2.

At least 0.6mL 

of standard 

solution for calibration.

1.

Place enough

standard calibration

solution to cover the

entire electrode

section.

2.

Press the

CAL button.

3.

After the display flashes "---",the 

standard calibration solution value will 

flash approx 10 times, then change to 

a fixed display of the value.

Calibrate at another point.

Flash   Light up

(The displayed value is an example.)

Calibration is complete

Perform the following procedure (a) and 
(b) before step 2.

<When performing more accurate calibration>

b.

 Place the standard 

solution for calibration so as 
to cover the entire electrode 
section again and leave it for 
approx. 30 seconds.

a.

Wipe away the 

standard calibration 

solution. 

At least 0.6mL of standard 

solution for calibration.

Calibration and Measurement Guidelines

◇When the electrodes are dry after long

period of not being used

◇Do not damage the electrodes.

Do not use metal tools.

Be careful not to

scratch the electrodes.

Tap water

Additional refills of standard solutions for calibration can be purchased from ATAGO (sold separately).
Contact ATAGO for recommended standard solutions.

[Part No.]  Standard solution for calibration 
RE-99210 pH4.01 

(volume: 500mL per bottle)

RE-99211 pH6.86 

(volume: 500mL per bottle)

RE-99213 pH9.18 

(volume: 500mL per bottle)

RE-99230 10mL pH4.01/pH6.86/pH9.18

[Part No.]  Standard solution for calibration 
RE-99210 pH4.01 

(volume: 500mL per bottle)

RE-99212 pH7.00 

(volume: 500mL per bottle)

RE-99214 pH10.01 

(volume: 500mL per bottle)

RE-99231 

10mL pH4.01/pH7.00/pH10.01 

CAL

CAL

-1-

-1-

6.86

7.00

1.

 Press and hold the

CAL button for 5 seconds

(while the unit is powered on).

2.

Press the START button to Select

a Calibration point.

3.

Press the CAL button

to confirm the selection.

-2-

End

4.

Calibration.

Calibration points 

-1-

4.01 6.86 9.18

Calibration points 

-2-

4.01 7.00 10.01

Select the Calibration option, either 1 or 2, according to values of the standards.

Calibration point display

How to Select a Calibration Option

END display

Now you can 
proceed  to 
Calibration. 

 Initial measurements may fluctuate with hot or cold samples.
Wait for the instrument to acclimate to the sample
temperature, then press the START button. Alternatively,
press the START button multiple times until measurements
become stable.

Access now

4311-E12

In just-a-minute

1. It requires 

only 1 minute!

 Simply by answering questions, warranty period is extended from 1 year 

to 2 years.

2. ATAGO Logger NFC can also be downloaded at the same time.

(The registration page can be accessed from ATAGO website.)

From 

1

 year to

2

years        

Free Extended Warranty

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